Broadband detection of methane and nitrous oxide using a distributed-feedback quantum cascade laser array and quartz-enhanced photoacoustic sensing

Here we report on the broadband detection of nitrous oxide (N2O) and methane (CH4) mixtures in dry nitrogen by using a quartz-enhanced photoacoustic (QEPAS) sensor exploiting an array of 32 distributed-feedback quantum cascade lasers, within a spectral emission range of 1190−1340 cm−1 as the excitat...

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Bibliographic Details
Main Authors: Marilena Giglio, Andrea Zifarelli, Angelo Sampaolo, Giansergio Menduni, Arianna Elefante, Romain Blanchard, Christian Pfluegl, Mark F. Witinski, Daryoosh Vakhshoori, Hongpeng Wu, Vittorio M.N. Passaro, Pietro Patimisco, Frank K. Tittel, Lei Dong, Vincenzo Spagnolo
Format: Article
Language:English
Published: Elsevier 2020-03-01
Series:Photoacoustics
Online Access:http://www.sciencedirect.com/science/article/pii/S2213597919300825
Description
Summary:Here we report on the broadband detection of nitrous oxide (N2O) and methane (CH4) mixtures in dry nitrogen by using a quartz-enhanced photoacoustic (QEPAS) sensor exploiting an array of 32 distributed-feedback quantum cascade lasers, within a spectral emission range of 1190−1340 cm−1 as the excitation source. Methane detection down to a minimum detection limit of 200 ppb at 10 s lock-in integration time was achieved. The sensor demonstrated a linear response in the range of 200−1000 ppm. Three different mixtures of N2O and CH4 in nitrogen at atmospheric pressure have been analyzed. The capability of the developed QEPAS sensor to selectively determine the N2O and CH4 concentrations was demonstrated, in spite of significant overlap in their respective absorption spectra in the investigated spectral range. Keywords: Broadband gas detection, Quartz-enhanced photoacoustic spectroscopy, Methane, Nitrous oxide, Distributed-feedback quantum cascade laser array
ISSN:2213-5979