Stereodynamic tetrahydrobiisoindole “NU-BIPHEP(O)”s: functionalization, rotational barriers and non-covalent interactions

Stereodynamic tetrahydrobiisoindole “NU-BIPHEP(O)”s: functionalization, rotational barriers and non-covalent interactions

Stereodynamic ligands offer intriguing possibilities in enantioselective catalysis. “NU-BIPHEPs” are a class of stereodynamic diphosphine ligands which are easily accessible via rhodium-catalyzed double [2 + 2 + 2] cycloadditions. This study explores the preparation of differently functionalized “NU...

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Bibliographic Details
Main Authors: Golo Storch, Sebastian Pallmann, Frank Rominger, Oliver Trapp
Format: Article
Language:English
Published: Beilstein-Institut 2016-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
atropisomer
enantioselective DHPLC
ligand design
non-covalent interactions
Okamoto phases
phosphine ligand
stereodynamic ligands
Online Access:https://doi.org/10.3762/bjoc.12.141

Internet

https://doi.org/10.3762/bjoc.12.141

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