Dichloridobis(7-amino-2,4-dimethyl-1,8-naphthyridine-κ2N,N′)cobalt(II) methanol disolvate

Dichloridobis(7-amino-2,4-dimethyl-1,8-naphthyridine-κ2N,N′)cobalt(II) methanol disolvate

The title compound, [CoCl2(C10H11N3)2]·2CH3OH, crystallizes with an elongated Co coordination polyhedron in a very distorted octahedral geometry. Both naphthyridine ligands coordinate to the Co atom via two N atoms in a bidentate chelating mode. The remaining coordination sites are occupied...

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Main Authors: Shouwen Jin, Ying Sun
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680706494X
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spelling doaj-0d18c264bdd54ac5a699b4f82e57f2a42020-11-25T00:52:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m136m13710.1107/S160053680706494XDichloridobis(7-amino-2,4-dimethyl-1,8-naphthyridine-κ2N,N′)cobalt(II) methanol disolvateShouwen JinYing SunThe title compound, [CoCl2(C10H11N3)2]·2CH3OH, crystallizes with an elongated Co coordination polyhedron in a very distorted octahedral geometry. Both naphthyridine ligands coordinate to the Co atom via two N atoms in a bidentate chelating mode. The remaining coordination sites are occupied by two Cl atoms. Two uncoordinated solvent methanol molecules are hydrogen bonded to the Cl atoms. Additional N—H...O, C—H...Cl and N—H...Cl hydrogen bonds, and π–π stacking interactions [centroid–centroid distance 3.664 (4) Å], give rise to a three-dimensional network structure.http://scripts.iucr.org/cgi-bin/paper?S160053680706494X
collection DOAJ
language English
format Article
sources DOAJ
author Shouwen Jin
Ying Sun
spellingShingle Shouwen Jin
Ying Sun
Dichloridobis(7-amino-2,4-dimethyl-1,8-naphthyridine-κ2N,N′)cobalt(II) methanol disolvate
Acta Crystallographica Section E
author_facet Shouwen Jin
Ying Sun
author_sort Shouwen Jin
title Dichloridobis(7-amino-2,4-dimethyl-1,8-naphthyridine-κ2N,N′)cobalt(II) methanol disolvate
title_short Dichloridobis(7-amino-2,4-dimethyl-1,8-naphthyridine-κ2N,N′)cobalt(II) methanol disolvate
title_full Dichloridobis(7-amino-2,4-dimethyl-1,8-naphthyridine-κ2N,N′)cobalt(II) methanol disolvate
title_fullStr Dichloridobis(7-amino-2,4-dimethyl-1,8-naphthyridine-κ2N,N′)cobalt(II) methanol disolvate
title_full_unstemmed Dichloridobis(7-amino-2,4-dimethyl-1,8-naphthyridine-κ2N,N′)cobalt(II) methanol disolvate
title_sort dichloridobis(7-amino-2,4-dimethyl-1,8-naphthyridine-κ2n,n′)cobalt(ii) methanol disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description The title compound, [CoCl2(C10H11N3)2]·2CH3OH, crystallizes with an elongated Co coordination polyhedron in a very distorted octahedral geometry. Both naphthyridine ligands coordinate to the Co atom via two N atoms in a bidentate chelating mode. The remaining coordination sites are occupied by two Cl atoms. Two uncoordinated solvent methanol molecules are hydrogen bonded to the Cl atoms. Additional N—H...O, C—H...Cl and N—H...Cl hydrogen bonds, and π–π stacking interactions [centroid–centroid distance 3.664 (4) Å], give rise to a three-dimensional network structure.
url http://scripts.iucr.org/cgi-bin/paper?S160053680706494X
work_keys_str_mv AT shouwenjin dichloridobis7amino24dimethyl18naphthyridine9542nn8242cobaltiimethanoldisolvate
AT yingsun dichloridobis7amino24dimethyl18naphthyridine9542nn8242cobaltiimethanoldisolvate
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