Dichloridobis(7-amino-2,4-dimethyl-1,8-naphthyridine-κ2N,N′)cobalt(II) methanol disolvate
The title compound, [CoCl2(C10H11N3)2]·2CH3OH, crystallizes with an elongated Co coordination polyhedron in a very distorted octahedral geometry. Both naphthyridine ligands coordinate to the Co atom via two N atoms in a bidentate chelating mode. The remaining coordination sites are occupied...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680706494X |
| Summary: | The title compound, [CoCl2(C10H11N3)2]·2CH3OH, crystallizes with an elongated Co coordination polyhedron in a very distorted octahedral geometry. Both naphthyridine ligands coordinate to the Co atom via two N atoms in a bidentate chelating mode. The remaining coordination sites are occupied by two Cl atoms. Two uncoordinated solvent methanol molecules are hydrogen bonded to the Cl atoms. Additional N—H...O, C—H...Cl and N—H...Cl hydrogen bonds, and π–π stacking interactions [centroid–centroid distance 3.664 (4) Å], give rise to a three-dimensional network structure. |
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| ISSN: | 1600-5368 |