Nonacarbonyl-1κ3C,2κ3C,3κ3C-μ-bis(diphenylarsino)methane-1:2κ2As:As'-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0)

Nonacarbonyl-1κ3C,2κ3C,3κ3C-μ-bis(diphenylarsino)methane-1:2κ2As:As'-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0)

In the title triangulo-triruthenium(0) compound, [Ru3(C25H22As2)(C6H12Cl3O3P)(CO)9], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to the Ru3...

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Main Authors: Omar bin Shawkataly, Imthyaz Ahmed Khan, Siti Syaida Sirat, Chin Sing Yeap, Hoong-Kun Fun
Format: Article
Language:English
Published: International Union of Crystallography 2010-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810026267
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spelling doaj-0cc9875c06f043fe8ad9e6cbbc5341d62020-11-25T00:17:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m929m93010.1107/S1600536810026267Nonacarbonyl-1κ3C,2κ3C,3κ3C-μ-bis(diphenylarsino)methane-1:2κ2As:As'-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0)Omar bin ShawkatalyImthyaz Ahmed KhanSiti Syaida SiratChin Sing YeapHoong-Kun FunIn the title triangulo-triruthenium(0) compound, [Ru3(C25H22As2)(C6H12Cl3O3P)(CO)9], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to the Ru3 triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. In the crystal packing, the molecules are linked by intermolecular C—H...O hydrogen bonds into a three-dimensional framework. Weak intermolecular C—H...π interactions further stabilize the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536810026267
collection DOAJ
language English
format Article
sources DOAJ
author Omar bin Shawkataly
Imthyaz Ahmed Khan
Siti Syaida Sirat
Chin Sing Yeap
Hoong-Kun Fun
spellingShingle Omar bin Shawkataly
Imthyaz Ahmed Khan
Siti Syaida Sirat
Chin Sing Yeap
Hoong-Kun Fun
Nonacarbonyl-1κ3C,2κ3C,3κ3C-μ-bis(diphenylarsino)methane-1:2κ2As:As'-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0)
Acta Crystallographica Section E
author_facet Omar bin Shawkataly
Imthyaz Ahmed Khan
Siti Syaida Sirat
Chin Sing Yeap
Hoong-Kun Fun
author_sort Omar bin Shawkataly
title Nonacarbonyl-1κ3C,2κ3C,3κ3C-μ-bis(diphenylarsino)methane-1:2κ2As:As'-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0)
title_short Nonacarbonyl-1κ3C,2κ3C,3κ3C-μ-bis(diphenylarsino)methane-1:2κ2As:As'-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0)
title_full Nonacarbonyl-1κ3C,2κ3C,3κ3C-μ-bis(diphenylarsino)methane-1:2κ2As:As'-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0)
title_fullStr Nonacarbonyl-1κ3C,2κ3C,3κ3C-μ-bis(diphenylarsino)methane-1:2κ2As:As'-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0)
title_full_unstemmed Nonacarbonyl-1κ3C,2κ3C,3κ3C-μ-bis(diphenylarsino)methane-1:2κ2As:As'-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0)
title_sort nonacarbonyl-1κ3c,2κ3c,3κ3c-μ-bis(diphenylarsino)methane-1:2κ2as:as'-[tris(2-chloroethyl) phosphite-3κp]-triangulo-triruthenium(0)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-08-01
description In the title triangulo-triruthenium(0) compound, [Ru3(C25H22As2)(C6H12Cl3O3P)(CO)9], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to the Ru3 triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. In the crystal packing, the molecules are linked by intermolecular C—H...O hydrogen bonds into a three-dimensional framework. Weak intermolecular C—H...π interactions further stabilize the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810026267
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AT imthyazahmedkhan nonacarbonyl1amp9543c2amp9543c3amp9543camp956bisdiphenylarsinomethane12amp9542asastris2chloroethylphosphite3amp954ptriangulotriruthenium0
AT sitisyaidasirat nonacarbonyl1amp9543c2amp9543c3amp9543camp956bisdiphenylarsinomethane12amp9542asastris2chloroethylphosphite3amp954ptriangulotriruthenium0
AT chinsingyeap nonacarbonyl1amp9543c2amp9543c3amp9543camp956bisdiphenylarsinomethane12amp9542asastris2chloroethylphosphite3amp954ptriangulotriruthenium0
AT hoongkunfun nonacarbonyl1amp9543c2amp9543c3amp9543camp956bisdiphenylarsinomethane12amp9542asastris2chloroethylphosphite3amp954ptriangulotriruthenium0
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