Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead

Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead

We developed a microwave-mediated continuous hydrogen production method from 2-PrOH using platinum on a spherical carbon-bead catalyst. The catalyst cartridge consisted of helical glass part, and straight glass part (helix−straight cartridge) was newly developed for the effective microwave...

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Main Authors: Tomohiro Ichikawa, Tomohiro Matsuo, Takumu Tachikawa, Wataru Teranishi, Tsuyoshi Yamada, Yoshinari Sawama, Yasunari Monguchi, Hironao Sajiki
Format: Article
Language:English
Published: MDPI AG 2019-07-01
Series:Catalysts
Subjects:
carbon
flow process
heterogeneous catalyst
hydrogen production
microwave chemistry
platinum
Online Access:https://www.mdpi.com/2073-4344/9/8/655
id doaj-0cc6e2a940d344debf13b11a1cc4708e
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spelling doaj-0cc6e2a940d344debf13b11a1cc4708e2020-11-24T21:24:16ZengMDPI AGCatalysts2073-43442019-07-019865510.3390/catal9080655catal9080655Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon BeadTomohiro Ichikawa0Tomohiro Matsuo1Takumu Tachikawa2Wataru Teranishi3Tsuyoshi Yamada4Yoshinari Sawama5Yasunari Monguchi6Hironao Sajiki7Laboratory of Organic Chemistry, Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, JapanLaboratory of Organic Chemistry, Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, JapanLaboratory of Organic Chemistry, Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, JapanLaboratory of Organic Chemistry, Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, JapanLaboratory of Organic Chemistry, Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, JapanLaboratory of Organic Chemistry, Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, JapanLaboratory of Organic Chemistry, Daiichi University of Pharmacy, 22-1, Tamagawa-cho, Minami-ku, Fukuoka 815-8511, JapanLaboratory of Organic Chemistry, Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, JapanWe developed a microwave-mediated continuous hydrogen production method from 2-PrOH using platinum on a spherical carbon-bead catalyst. The catalyst cartridge consisted of helical glass part, and straight glass part (helix−straight cartridge) was newly developed for the effective microwave heating of 2-PrOH in the presence of 5% Pt/CB. The microwave resonance was properly adjusted within 2.4−2.5 GHz using the helix−straight cartridge with the glass resonance-adjuster tube. The reaction was conducted by the irradiation of only 10 W of single-frequency microwaves and the catalyst was used continuously for at least 13 h without any loss of catalyst activity.https://www.mdpi.com/2073-4344/9/8/655carbonflow processheterogeneous catalysthydrogen productionmicrowave chemistryplatinum
collection DOAJ
language English
format Article
sources DOAJ
author Tomohiro Ichikawa
Tomohiro Matsuo
Takumu Tachikawa
Wataru Teranishi
Tsuyoshi Yamada
Yoshinari Sawama
Yasunari Monguchi
Hironao Sajiki
spellingShingle Tomohiro Ichikawa
Tomohiro Matsuo
Takumu Tachikawa
Wataru Teranishi
Tsuyoshi Yamada
Yoshinari Sawama
Yasunari Monguchi
Hironao Sajiki
Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead
Catalysts
carbon
flow process
heterogeneous catalyst
hydrogen production
microwave chemistry
platinum
author_facet Tomohiro Ichikawa
Tomohiro Matsuo
Takumu Tachikawa
Wataru Teranishi
Tsuyoshi Yamada
Yoshinari Sawama
Yasunari Monguchi
Hironao Sajiki
author_sort Tomohiro Ichikawa
title Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead
title_short Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead
title_full Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead
title_fullStr Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead
title_full_unstemmed Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead
title_sort microwave-mediated continuous hydrogen abstraction reaction from 2-proh catalyzed by platinum on carbon bead
publisher MDPI AG
series Catalysts
issn 2073-4344
publishDate 2019-07-01
description We developed a microwave-mediated continuous hydrogen production method from 2-PrOH using platinum on a spherical carbon-bead catalyst. The catalyst cartridge consisted of helical glass part, and straight glass part (helix−straight cartridge) was newly developed for the effective microwave heating of 2-PrOH in the presence of 5% Pt/CB. The microwave resonance was properly adjusted within 2.4−2.5 GHz using the helix−straight cartridge with the glass resonance-adjuster tube. The reaction was conducted by the irradiation of only 10 W of single-frequency microwaves and the catalyst was used continuously for at least 13 h without any loss of catalyst activity.
topic carbon
flow process
heterogeneous catalyst
hydrogen production
microwave chemistry
platinum
url https://www.mdpi.com/2073-4344/9/8/655
work_keys_str_mv AT tomohiroichikawa microwavemediatedcontinuoushydrogenabstractionreactionfrom2prohcatalyzedbyplatinumoncarbonbead
AT tomohiromatsuo microwavemediatedcontinuoushydrogenabstractionreactionfrom2prohcatalyzedbyplatinumoncarbonbead
AT takumutachikawa microwavemediatedcontinuoushydrogenabstractionreactionfrom2prohcatalyzedbyplatinumoncarbonbead
AT wataruteranishi microwavemediatedcontinuoushydrogenabstractionreactionfrom2prohcatalyzedbyplatinumoncarbonbead
AT tsuyoshiyamada microwavemediatedcontinuoushydrogenabstractionreactionfrom2prohcatalyzedbyplatinumoncarbonbead
AT yoshinarisawama microwavemediatedcontinuoushydrogenabstractionreactionfrom2prohcatalyzedbyplatinumoncarbonbead
AT yasunarimonguchi microwavemediatedcontinuoushydrogenabstractionreactionfrom2prohcatalyzedbyplatinumoncarbonbead
AT hironaosajiki microwavemediatedcontinuoushydrogenabstractionreactionfrom2prohcatalyzedbyplatinumoncarbonbead
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