Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead

Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead

We developed a microwave-mediated continuous hydrogen production method from 2-PrOH using platinum on a spherical carbon-bead catalyst. The catalyst cartridge consisted of helical glass part, and straight glass part (helix−straight cartridge) was newly developed for the effective microwave...

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Bibliographic Details
Main Authors: Tomohiro Ichikawa, Tomohiro Matsuo, Takumu Tachikawa, Wataru Teranishi, Tsuyoshi Yamada, Yoshinari Sawama, Yasunari Monguchi, Hironao Sajiki
Format: Article
Language:English
Published: MDPI AG 2019-07-01
Series:Catalysts
Subjects:
carbon
flow process
heterogeneous catalyst
hydrogen production
microwave chemistry
platinum
Online Access:https://www.mdpi.com/2073-4344/9/8/655
Description
Summary:We developed a microwave-mediated continuous hydrogen production method from 2-PrOH using platinum on a spherical carbon-bead catalyst. The catalyst cartridge consisted of helical glass part, and straight glass part (helix−straight cartridge) was newly developed for the effective microwave heating of 2-PrOH in the presence of 5% Pt/CB. The microwave resonance was properly adjusted within 2.4−2.5 GHz using the helix−straight cartridge with the glass resonance-adjuster tube. The reaction was conducted by the irradiation of only 10 W of single-frequency microwaves and the catalyst was used continuously for at least 13 h without any loss of catalyst activity.
ISSN:2073-4344

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