UVB LEDs Grown by Molecular Beam Epitaxy Using AlGaN Quantum Dots

AlGaN based light emitting diodes (LEDs) will play a key role for the development of applications in the ultra-violet (UV). In the UVB region (280–320 nm), phototherapy and plant lighting are among the targeted uses. However, UVB LED performances still need to be improved to reach commercial markets...

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Main Authors: Julien Brault, Mohamed Al Khalfioui, Samuel Matta, Thi Huong Ngo, Sébastien Chenot, Mathieu Leroux, Pierre Valvin, Bernard Gil
Format: Article
Language:English
Published: MDPI AG 2020-11-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/10/12/1097
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spelling doaj-0caaaa98e2d843ebb2578ce0e8690ce22020-12-01T00:00:40ZengMDPI AGCrystals2073-43522020-11-01101097109710.3390/cryst10121097UVB LEDs Grown by Molecular Beam Epitaxy Using AlGaN Quantum DotsJulien Brault0Mohamed Al Khalfioui1Samuel Matta2Thi Huong Ngo3Sébastien Chenot4Mathieu Leroux5Pierre Valvin6Bernard Gil7CNRS, Université Côte d’Azur, 06108 Nice CEDEX 2, FranceCNRS, Université Côte d’Azur, 06108 Nice CEDEX 2, FranceCNRS, Université Côte d’Azur, 06108 Nice CEDEX 2, FranceLaboratoire Charles Coulomb and Université Montpellier 2, UMR 5221, 34095 Montpellier, FranceCNRS, Université Côte d’Azur, 06108 Nice CEDEX 2, FranceCNRS, Université Côte d’Azur, 06108 Nice CEDEX 2, FranceLaboratoire Charles Coulomb and Université Montpellier 2, UMR 5221, 34095 Montpellier, FranceLaboratoire Charles Coulomb and Université Montpellier 2, UMR 5221, 34095 Montpellier, FranceAlGaN based light emitting diodes (LEDs) will play a key role for the development of applications in the ultra-violet (UV). In the UVB region (280–320 nm), phototherapy and plant lighting are among the targeted uses. However, UVB LED performances still need to be improved to reach commercial markets. In particular, the design and the fabrication process of the active region are central elements that affect the LED internal quantum efficiency (IQE). We propose the use of nanometer-sized epitaxial islands (i.e., so called quantum dots (QDs)) to enhance the carrier localization and improve the IQE of molecular beam epitaxy (MBE) grown UVB LEDs using sapphire substrates with thin sub-µm AlN templates. Taking advantage of the epitaxial stress, AlGaN QDs with nanometer-sized (≤10 nm) lateral and vertical dimensions have been grown by MBE. The IQE of the QDs has been deduced from temperature dependent and time resolved photoluminescence measurements. Room temperature IQE values around 5 to 10% have been found in the 290–320 nm range. QD-based UVB LEDs were then fabricated and characterized by electrical and electroluminescence measurements. On-wafer measurements showed optical powers up to 0.25 mW with external quantum efficiency (EQE) values around 0.1% in the 305–320 nm range.https://www.mdpi.com/2073-4352/10/12/1097light emitting diodesultra-violet emissionmolecular beam epitaxyAlGaNquantum dotsinternal quantum efficiency
collection DOAJ
language English
format Article
sources DOAJ
author Julien Brault
Mohamed Al Khalfioui
Samuel Matta
Thi Huong Ngo
Sébastien Chenot
Mathieu Leroux
Pierre Valvin
Bernard Gil
spellingShingle Julien Brault
Mohamed Al Khalfioui
Samuel Matta
Thi Huong Ngo
Sébastien Chenot
Mathieu Leroux
Pierre Valvin
Bernard Gil
UVB LEDs Grown by Molecular Beam Epitaxy Using AlGaN Quantum Dots
Crystals
light emitting diodes
ultra-violet emission
molecular beam epitaxy
AlGaN
quantum dots
internal quantum efficiency
author_facet Julien Brault
Mohamed Al Khalfioui
Samuel Matta
Thi Huong Ngo
Sébastien Chenot
Mathieu Leroux
Pierre Valvin
Bernard Gil
author_sort Julien Brault
title UVB LEDs Grown by Molecular Beam Epitaxy Using AlGaN Quantum Dots
title_short UVB LEDs Grown by Molecular Beam Epitaxy Using AlGaN Quantum Dots
title_full UVB LEDs Grown by Molecular Beam Epitaxy Using AlGaN Quantum Dots
title_fullStr UVB LEDs Grown by Molecular Beam Epitaxy Using AlGaN Quantum Dots
title_full_unstemmed UVB LEDs Grown by Molecular Beam Epitaxy Using AlGaN Quantum Dots
title_sort uvb leds grown by molecular beam epitaxy using algan quantum dots
publisher MDPI AG
series Crystals
issn 2073-4352
publishDate 2020-11-01
description AlGaN based light emitting diodes (LEDs) will play a key role for the development of applications in the ultra-violet (UV). In the UVB region (280–320 nm), phototherapy and plant lighting are among the targeted uses. However, UVB LED performances still need to be improved to reach commercial markets. In particular, the design and the fabrication process of the active region are central elements that affect the LED internal quantum efficiency (IQE). We propose the use of nanometer-sized epitaxial islands (i.e., so called quantum dots (QDs)) to enhance the carrier localization and improve the IQE of molecular beam epitaxy (MBE) grown UVB LEDs using sapphire substrates with thin sub-µm AlN templates. Taking advantage of the epitaxial stress, AlGaN QDs with nanometer-sized (≤10 nm) lateral and vertical dimensions have been grown by MBE. The IQE of the QDs has been deduced from temperature dependent and time resolved photoluminescence measurements. Room temperature IQE values around 5 to 10% have been found in the 290–320 nm range. QD-based UVB LEDs were then fabricated and characterized by electrical and electroluminescence measurements. On-wafer measurements showed optical powers up to 0.25 mW with external quantum efficiency (EQE) values around 0.1% in the 305–320 nm range.
topic light emitting diodes
ultra-violet emission
molecular beam epitaxy
AlGaN
quantum dots
internal quantum efficiency
url https://www.mdpi.com/2073-4352/10/12/1097
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