Water Behavior of Emulsions Stabilized by Modified Potato Starch

• Main Authors: Zuzanna Małyszek, Jacek Lewandowicz, Joanna Le Thanh-Blicharz, Katarzyna Walkowiak, Przemysław Łukasz Kowalczewski, Hanna Maria Baranowska
• Format: Article
• Language: English
• Published: MDPI AG 2021-07-01
• Series: Polymers
• Subjects: emulsion; nuclear magnetic resonance; LF NMR; relaxometry; modified starches; water dynamics
• Online Access: https://www.mdpi.com/2073-4360/13/13/2200

Starch is a widely known and used emulsion stabilizer. In order to improve its properties, various types of modifications are made that change its ability to emulsify and stabilize. This paper describes the analysis of the molecular dynamics of water using low-field nuclear magnetic resonance (LF NMR) in oil-in-water emulsions obtained with the use of physically or chemically modified potato starch. The analysis of changes in spin-spin and spin-lattice relaxation times depending on the temperature allowed the activation energy value of water molecules in the analyzed emulsions to be determined. It has been shown that the presence of starch influences the values of spin-lattice T₁ and spin-spin T₂ relaxation times, both in the water and the oil phase, and the observed changes largely depended on the type of starch modification. Both types of analyzed starches also differently influenced the energy of activation of rotational movements of water molecules. On the basis of the analyses carried out with the use of LF NMR, it can be concluded that physically modified starch acts not only as a stabilizer, but also as an emulsifier, while acetylated starch does not exhibit good emulsifying properties.