Transition metal-like carbocatalyst

Metal-free catalysts can offer uniquely different activity and selectivity from transition metal-based counterparts. Here, the authors report metal-free nitrogen-assembly carbon with closely-placed nitrogen as active sites, achieving catalytic cleavage of strong bonds including H-H, C-O and C-H.

Bibliographic Details
Main Authors:	Zhicheng Luo, Renfeng Nie, Vy T. Nguyen, Abhranil Biswas, Ranjan K. Behera, Xun Wu, Takeshi Kobayashi, Aaron Sadow, Bin Wang, Wenyu Huang, Long Qi
Format:	Article
Language:	English
Published:	Nature Publishing Group 2020-08-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-020-17909-8

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spelling	doaj-0b6c04211fde4a31acd09bcc875c431f2021-08-15T11:40:50ZengNature Publishing GroupNature Communications2041-17232020-08-011111910.1038/s41467-020-17909-8Transition metal-like carbocatalystZhicheng Luo0Renfeng Nie1Vy T. Nguyen2Abhranil Biswas3Ranjan K. Behera4Xun Wu5Takeshi Kobayashi6Aaron Sadow7Bin Wang8Wenyu Huang9Long Qi10U.S. DOE Ames Laboratory, Iowa State UniversityDepartment of Chemistry, Iowa State UniversitySchool of Chemical, Biological and Materials Engineering, University of OklahomaDepartment of Chemistry, Iowa State UniversityDepartment of Chemistry, Iowa State UniversityDepartment of Chemistry, Iowa State UniversityU.S. DOE Ames Laboratory, Iowa State UniversityU.S. DOE Ames Laboratory, Iowa State UniversitySchool of Chemical, Biological and Materials Engineering, University of OklahomaDepartment of Chemistry, Iowa State UniversityU.S. DOE Ames Laboratory, Iowa State UniversityMetal-free catalysts can offer uniquely different activity and selectivity from transition metal-based counterparts. Here, the authors report metal-free nitrogen-assembly carbon with closely-placed nitrogen as active sites, achieving catalytic cleavage of strong bonds including H-H, C-O and C-H.https://doi.org/10.1038/s41467-020-17909-8
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Zhicheng Luo Renfeng Nie Vy T. Nguyen Abhranil Biswas Ranjan K. Behera Xun Wu Takeshi Kobayashi Aaron Sadow Bin Wang Wenyu Huang Long Qi
spellingShingle	Zhicheng Luo Renfeng Nie Vy T. Nguyen Abhranil Biswas Ranjan K. Behera Xun Wu Takeshi Kobayashi Aaron Sadow Bin Wang Wenyu Huang Long Qi Transition metal-like carbocatalyst Nature Communications
author_facet	Zhicheng Luo Renfeng Nie Vy T. Nguyen Abhranil Biswas Ranjan K. Behera Xun Wu Takeshi Kobayashi Aaron Sadow Bin Wang Wenyu Huang Long Qi
author_sort	Zhicheng Luo
title	Transition metal-like carbocatalyst
title_short	Transition metal-like carbocatalyst
title_full	Transition metal-like carbocatalyst
title_fullStr	Transition metal-like carbocatalyst
title_full_unstemmed	Transition metal-like carbocatalyst
title_sort	transition metal-like carbocatalyst
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2020-08-01
description	Metal-free catalysts can offer uniquely different activity and selectivity from transition metal-based counterparts. Here, the authors report metal-free nitrogen-assembly carbon with closely-placed nitrogen as active sites, achieving catalytic cleavage of strong bonds including H-H, C-O and C-H.
url	https://doi.org/10.1038/s41467-020-17909-8
work_keys_str_mv	AT zhichengluo transitionmetallikecarbocatalyst AT renfengnie transitionmetallikecarbocatalyst AT vytnguyen transitionmetallikecarbocatalyst AT abhranilbiswas transitionmetallikecarbocatalyst AT ranjankbehera transitionmetallikecarbocatalyst AT xunwu transitionmetallikecarbocatalyst AT takeshikobayashi transitionmetallikecarbocatalyst AT aaronsadow transitionmetallikecarbocatalyst AT binwang transitionmetallikecarbocatalyst AT wenyuhuang transitionmetallikecarbocatalyst AT longqi transitionmetallikecarbocatalyst
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Transition metal-like carbocatalyst

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