catena-Poly[[(tetrahydrofuran-&#954;O)lithium(I)]-bis(&#956;-trimethylsilanolato-&#954;2O:O)-gallium(III)-bis(&#956;-trimethylsilanolato-&#954;2O:O)-[(tetrahydrofuran-&#954;O)lithium(I)]-&#956;-bromido]

The title chain polymer compound, [GaLi2Br(C3H9OSi)4(C4H8O)2]n, was obtained in the reaction of GaBr3 with Me3SiOLi in toluene/tetrahydrofuran. The GaIII atom, located on a twofold rotation axis, is coordinated by four trimethylsilanolate ligands and has a distorted tetrahedral geometry. The LiI ato...

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Bibliographic Details
Main Authors:	Jerzy Pikies, Katarzyna Baranowska, Rafa&#322; Grubba
Format:	Article
Language:	English
Published:	International Union of Crystallography 2010-10-01
Series:	Acta Crystallographica Section E
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S1600536810035518

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record_format	Article
spelling	doaj-0b3da7330a0d456a9eac1a5f0062eb162020-11-25T01:37:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1242m124210.1107/S1600536810035518catena-Poly[[(tetrahydrofuran-&#954;O)lithium(I)]-bis(&#956;-trimethylsilanolato-&#954;2O:O)-gallium(III)-bis(&#956;-trimethylsilanolato-&#954;2O:O)-[(tetrahydrofuran-&#954;O)lithium(I)]-&#956;-bromido]Jerzy PikiesKatarzyna BaranowskaRafa&#322; GrubbaThe title chain polymer compound, [GaLi2Br(C3H9OSi)4(C4H8O)2]n, was obtained in the reaction of GaBr3 with Me3SiOLi in toluene/tetrahydrofuran. The GaIII atom, located on a twofold rotation axis, is coordinated by four trimethylsilanolate ligands and has a distorted tetrahedral geometry. The LiI atom is four coordinated by one bridging Br atom located on an inversion centre, two trimethylsilanolate ligands and one tetrahydrofurane molecule in a distorted tetrahedral geometry. The polymeric chains extend along [001]. The tetrahydrofurane molecule is disordered over two positions with site-occupancy factors of 0.57&#8197;(2) and 0.43&#8197;(2). http://scripts.iucr.org/cgi-bin/paper?S1600536810035518
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Jerzy Pikies Katarzyna Baranowska Rafa&#322; Grubba
spellingShingle	Jerzy Pikies Katarzyna Baranowska Rafa&#322; Grubba catena-Poly[[(tetrahydrofuran-&#954;O)lithium(I)]-bis(&#956;-trimethylsilanolato-&#954;2O:O)-gallium(III)-bis(&#956;-trimethylsilanolato-&#954;2O:O)-[(tetrahydrofuran-&#954;O)lithium(I)]-&#956;-bromido] Acta Crystallographica Section E
author_facet	Jerzy Pikies Katarzyna Baranowska Rafa&#322; Grubba
author_sort	Jerzy Pikies
title	catena-Poly[[(tetrahydrofuran-&#954;O)lithium(I)]-bis(&#956;-trimethylsilanolato-&#954;2O:O)-gallium(III)-bis(&#956;-trimethylsilanolato-&#954;2O:O)-[(tetrahydrofuran-&#954;O)lithium(I)]-&#956;-bromido]
title_short	catena-Poly[[(tetrahydrofuran-&#954;O)lithium(I)]-bis(&#956;-trimethylsilanolato-&#954;2O:O)-gallium(III)-bis(&#956;-trimethylsilanolato-&#954;2O:O)-[(tetrahydrofuran-&#954;O)lithium(I)]-&#956;-bromido]
title_full	catena-Poly[[(tetrahydrofuran-&#954;O)lithium(I)]-bis(&#956;-trimethylsilanolato-&#954;2O:O)-gallium(III)-bis(&#956;-trimethylsilanolato-&#954;2O:O)-[(tetrahydrofuran-&#954;O)lithium(I)]-&#956;-bromido]
title_fullStr	catena-Poly[[(tetrahydrofuran-&#954;O)lithium(I)]-bis(&#956;-trimethylsilanolato-&#954;2O:O)-gallium(III)-bis(&#956;-trimethylsilanolato-&#954;2O:O)-[(tetrahydrofuran-&#954;O)lithium(I)]-&#956;-bromido]
title_full_unstemmed	catena-Poly[[(tetrahydrofuran-&#954;O)lithium(I)]-bis(&#956;-trimethylsilanolato-&#954;2O:O)-gallium(III)-bis(&#956;-trimethylsilanolato-&#954;2O:O)-[(tetrahydrofuran-&#954;O)lithium(I)]-&#956;-bromido]
title_sort	catena-poly[[(tetrahydrofuran-&#954;o)lithium(i)]-bis(&#956;-trimethylsilanolato-&#954;2o:o)-gallium(iii)-bis(&#956;-trimethylsilanolato-&#954;2o:o)-[(tetrahydrofuran-&#954;o)lithium(i)]-&#956;-bromido]
publisher	International Union of Crystallography
series	Acta Crystallographica Section E
issn	1600-5368
publishDate	2010-10-01
description	The title chain polymer compound, [GaLi2Br(C3H9OSi)4(C4H8O)2]n, was obtained in the reaction of GaBr3 with Me3SiOLi in toluene/tetrahydrofuran. The GaIII atom, located on a twofold rotation axis, is coordinated by four trimethylsilanolate ligands and has a distorted tetrahedral geometry. The LiI atom is four coordinated by one bridging Br atom located on an inversion centre, two trimethylsilanolate ligands and one tetrahydrofurane molecule in a distorted tetrahedral geometry. The polymeric chains extend along [001]. The tetrahydrofurane molecule is disordered over two positions with site-occupancy factors of 0.57&#8197;(2) and 0.43&#8197;(2).
url	http://scripts.iucr.org/cgi-bin/paper?S1600536810035518
work_keys_str_mv	AT jerzypikies catenapolytetrahydrofuranamp954olithiumibisamp956trimethylsilanolatoamp9542oogalliumiiibisamp956trimethylsilanolatoamp9542ootetrahydrofuranamp954olithiumiamp956bromido AT katarzynabaranowska catenapolytetrahydrofuranamp954olithiumibisamp956trimethylsilanolatoamp9542oogalliumiiibisamp956trimethylsilanolatoamp9542ootetrahydrofuranamp954olithiumiamp956bromido AT rafaamp322grubba catenapolytetrahydrofuranamp954olithiumibisamp956trimethylsilanolatoamp9542oogalliumiiibisamp956trimethylsilanolatoamp9542ootetrahydrofuranamp954olithiumiamp956bromido
_version_	1725055867866316800

catena-Poly[[(tetrahydrofuran-&amp;#954;O)lithium(I)]-bis(&amp;#956;-trimethylsilanolato-&amp;#954;2O:O)-gallium(III)-bis(&amp;#956;-trimethylsilanolato-&amp;#954;2O:O)-[(tetrahydrofuran-&amp;#954;O)lithium(I)]-&amp;#956;-bromido]

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