Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaquabis(pyridine-2,4-dicarboxylato-κ2N,O2)zincate(II) dihydrate

Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaquabis(pyridine-2,4-dicarboxylato-κ2N,O2)zincate(II) dihydrate

In the title compound, (C4H8N3O)2[Zn(C7H3NO4)2(H2O)2]·2H2O, the ZnII ion is six-coordinated in a distorted octahedral geometry by two pyridine-2,4-dicarboxylate (pydc) ligands in the equatorial plane and two water molecules in the axial positions. The pydc ligands act as bidentate chela...

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Main Authors: Hossein Aghabozorg, Fatemeh Jafarbak, Masoud Mirzaei, Behrouz Notash
Format: Article
Language:English
Published: International Union of Crystallography 2011-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811008452
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spelling doaj-0b1c2af17b43498abe34dd4c75831c2e2020-11-25T01:35:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-04-01674m435m43610.1107/S1600536811008452Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaquabis(pyridine-2,4-dicarboxylato-κ2N,O2)zincate(II) dihydrateHossein AghabozorgFatemeh JafarbakMasoud MirzaeiBehrouz NotashIn the title compound, (C4H8N3O)2[Zn(C7H3NO4)2(H2O)2]·2H2O, the ZnII ion is six-coordinated in a distorted octahedral geometry by two pyridine-2,4-dicarboxylate (pydc) ligands in the equatorial plane and two water molecules in the axial positions. The pydc ligands act as bidentate chelating ligands through one carboxylate O atom and the pyridine N atom. Intermolecular N—H...O, O—H...O and weak C—H...O hydrogen bonds stabilize the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536811008452
collection DOAJ
language English
format Article
sources DOAJ
author Hossein Aghabozorg
Fatemeh Jafarbak
Masoud Mirzaei
Behrouz Notash
spellingShingle Hossein Aghabozorg
Fatemeh Jafarbak
Masoud Mirzaei
Behrouz Notash
Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaquabis(pyridine-2,4-dicarboxylato-κ2N,O2)zincate(II) dihydrate
Acta Crystallographica Section E
author_facet Hossein Aghabozorg
Fatemeh Jafarbak
Masoud Mirzaei
Behrouz Notash
author_sort Hossein Aghabozorg
title Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaquabis(pyridine-2,4-dicarboxylato-κ2N,O2)zincate(II) dihydrate
title_short Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaquabis(pyridine-2,4-dicarboxylato-κ2N,O2)zincate(II) dihydrate
title_full Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaquabis(pyridine-2,4-dicarboxylato-κ2N,O2)zincate(II) dihydrate
title_fullStr Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaquabis(pyridine-2,4-dicarboxylato-κ2N,O2)zincate(II) dihydrate
title_full_unstemmed Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaquabis(pyridine-2,4-dicarboxylato-κ2N,O2)zincate(II) dihydrate
title_sort bis(1-methyl-4-oxoimidazolidin-2-iminium) diaquabis(pyridine-2,4-dicarboxylato-κ2n,o2)zincate(ii) dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-04-01
description In the title compound, (C4H8N3O)2[Zn(C7H3NO4)2(H2O)2]·2H2O, the ZnII ion is six-coordinated in a distorted octahedral geometry by two pyridine-2,4-dicarboxylate (pydc) ligands in the equatorial plane and two water molecules in the axial positions. The pydc ligands act as bidentate chelating ligands through one carboxylate O atom and the pyridine N atom. Intermolecular N—H...O, O—H...O and weak C—H...O hydrogen bonds stabilize the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811008452
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AT masoudmirzaei bis1methyl4oxoimidazolidin2iminiumdiaquabispyridine24dicarboxylatoamp9542no2zincateiidihydrate
AT behrouznotash bis1methyl4oxoimidazolidin2iminiumdiaquabispyridine24dicarboxylatoamp9542no2zincateiidihydrate
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