Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaquabis(pyridine-2,4-dicarboxylato-κ2N,O2)zincate(II) dihydrate

Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaquabis(pyridine-2,4-dicarboxylato-κ2N,O2)zincate(II) dihydrate

In the title compound, (C4H8N3O)2[Zn(C7H3NO4)2(H2O)2]·2H2O, the ZnII ion is six-coordinated in a distorted octahedral geometry by two pyridine-2,4-dicarboxylate (pydc) ligands in the equatorial plane and two water molecules in the axial positions. The pydc ligands act as bidentate chela...

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Bibliographic Details
Main Authors: Hossein Aghabozorg, Fatemeh Jafarbak, Masoud Mirzaei, Behrouz Notash
Format: Article
Language:English
Published: International Union of Crystallography 2011-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811008452
Description
Summary:In the title compound, (C4H8N3O)2[Zn(C7H3NO4)2(H2O)2]·2H2O, the ZnII ion is six-coordinated in a distorted octahedral geometry by two pyridine-2,4-dicarboxylate (pydc) ligands in the equatorial plane and two water molecules in the axial positions. The pydc ligands act as bidentate chelating ligands through one carboxylate O atom and the pyridine N atom. Intermolecular N—H...O, O—H...O and weak C—H...O hydrogen bonds stabilize the crystal structure.
ISSN:1600-5368

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