Bis{2-[(guanidinoimino)methyl]phenolato-κ3N,N′,O}cobalt(III) chloride hemihydrate
The title compound, [Co(C8H9N4O)2]Cl·0.5H2O, is a solvatomorph of the corresponding trihydrate. Unlike in the structure of the latter compound, there are two different cations in the asymmetric unit of the title compound. The ligand molecules are deprotonated at the phenol O atom and octahe...
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| Language: | English |
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International Union of Crystallography
2013-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813004534 |
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doaj-0a3fec3e54414bffa0939cbb32e562512020-11-25T01:56:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-03-01693m165m16610.1107/S1600536813004534Bis{2-[(guanidinoimino)methyl]phenolato-κ3N,N′,O}cobalt(III) chloride hemihydrateBrian W. SkeltonOlga Yu. VassilyevaVladimir N. KokozayElena A. BuvayloThe title compound, [Co(C8H9N4O)2]Cl·0.5H2O, is a solvatomorph of the corresponding trihydrate. Unlike in the structure of the latter compound, there are two different cations in the asymmetric unit of the title compound. The ligand molecules are deprotonated at the phenol O atom and octahedrally coordinate the CoIII atoms through the azomethine N and phenolate O atoms in a mer configuration. In the crystal, the cations, chloride ions and lattice water molecules are linked by N—H...O, N—H...Cl, O—H...Cl and O—H...O interactions, forming a two-dimensional network parallel to (10-1).http://scripts.iucr.org/cgi-bin/paper?S1600536813004534 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Brian W. Skelton Olga Yu. Vassilyeva Vladimir N. Kokozay Elena A. Buvaylo |
| spellingShingle |
Brian W. Skelton Olga Yu. Vassilyeva Vladimir N. Kokozay Elena A. Buvaylo Bis{2-[(guanidinoimino)methyl]phenolato-κ3N,N′,O}cobalt(III) chloride hemihydrate Acta Crystallographica Section E |
| author_facet |
Brian W. Skelton Olga Yu. Vassilyeva Vladimir N. Kokozay Elena A. Buvaylo |
| author_sort |
Brian W. Skelton |
| title |
Bis{2-[(guanidinoimino)methyl]phenolato-κ3N,N′,O}cobalt(III) chloride hemihydrate |
| title_short |
Bis{2-[(guanidinoimino)methyl]phenolato-κ3N,N′,O}cobalt(III) chloride hemihydrate |
| title_full |
Bis{2-[(guanidinoimino)methyl]phenolato-κ3N,N′,O}cobalt(III) chloride hemihydrate |
| title_fullStr |
Bis{2-[(guanidinoimino)methyl]phenolato-κ3N,N′,O}cobalt(III) chloride hemihydrate |
| title_full_unstemmed |
Bis{2-[(guanidinoimino)methyl]phenolato-κ3N,N′,O}cobalt(III) chloride hemihydrate |
| title_sort |
bis{2-[(guanidinoimino)methyl]phenolato-κ3n,n′,o}cobalt(iii) chloride hemihydrate |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2013-03-01 |
| description |
The title compound, [Co(C8H9N4O)2]Cl·0.5H2O, is a solvatomorph of the corresponding trihydrate. Unlike in the structure of the latter compound, there are two different cations in the asymmetric unit of the title compound. The ligand molecules are deprotonated at the phenol O atom and octahedrally coordinate the CoIII atoms through the azomethine N and phenolate O atoms in a mer configuration. In the crystal, the cations, chloride ions and lattice water molecules are linked by N—H...O, N—H...Cl, O—H...Cl and O—H...O interactions, forming a two-dimensional network parallel to (10-1). |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536813004534 |
| work_keys_str_mv |
AT brianwskelton bis2guanidinoiminomethylphenolato9543nn8242ocobaltiiichloridehemihydrate AT olgayuvassilyeva bis2guanidinoiminomethylphenolato9543nn8242ocobaltiiichloridehemihydrate AT vladimirnkokozay bis2guanidinoiminomethylphenolato9543nn8242ocobaltiiichloridehemihydrate AT elenaabuvaylo bis2guanidinoiminomethylphenolato9543nn8242ocobaltiiichloridehemihydrate |
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