Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound
New inorganic-organic hybrid [(C3H7)4N]2Hg2Cl6 compound was obtained and characterised by single-crystal X-ray diffraction, infrared, and impedance spectroscopy. The latter crystallizes in the monoclinic system (space group C 2/c, ) with the following unit cell dimensions: (1) Å, (6) Å, (2) Å, and (...
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doaj-0a38f90b2499486f94746e005c8d27ab2020-11-25T00:51:47ZengHindawi LimitedJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/435462435462Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid CompoundA. Oueslati0I. Chaabane1K. Adil2F. Hlel3Laboratoire de l'État Solide, Faculté des Sciences de Sfax, Université de Sfax, 3000 Sfax, TunisiaLaboratoire de l'État Solide, Faculté des Sciences de Sfax, Université de Sfax, 3000 Sfax, TunisiaLaboratoire des Oxydes et Fluorures, Université du Maine, Avenue Olivier Messiaen, 72085 Le Mans Cedex 05, FranceLaboratoire de l'État Solide, Faculté des Sciences de Sfax, Université de Sfax, 3000 Sfax, TunisiaNew inorganic-organic hybrid [(C3H7)4N]2Hg2Cl6 compound was obtained and characterised by single-crystal X-ray diffraction, infrared, and impedance spectroscopy. The latter crystallizes in the monoclinic system (space group C 2/c, ) with the following unit cell dimensions: (1) Å, (6) Å, (2) Å, and (2). Besides, its structure was solved using 84860 independent reflections leading to . Electrical properties of the material were studied using impedance spectroscopic technique at different temperatures in the frequency range of 209 Hz to 5 MHz. Detailed analysis of the impedance spectrum suggested that the electrical properties of the material are strongly temperature-dependent. The Nyquist plots clearly showed the presence of bulk and grain boundary effect in the compound.http://dx.doi.org/10.1155/2013/435462 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
A. Oueslati I. Chaabane K. Adil F. Hlel |
spellingShingle |
A. Oueslati I. Chaabane K. Adil F. Hlel Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound Journal of Chemistry |
author_facet |
A. Oueslati I. Chaabane K. Adil F. Hlel |
author_sort |
A. Oueslati |
title |
Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound |
title_short |
Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound |
title_full |
Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound |
title_fullStr |
Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound |
title_full_unstemmed |
Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound |
title_sort |
structural characterization and infrared and electrical properties of the new inorganic-organic hybrid compound |
publisher |
Hindawi Limited |
series |
Journal of Chemistry |
issn |
2090-9063 2090-9071 |
publishDate |
2013-01-01 |
description |
New inorganic-organic hybrid [(C3H7)4N]2Hg2Cl6 compound was obtained and characterised by single-crystal X-ray diffraction, infrared, and impedance spectroscopy. The latter crystallizes in the monoclinic system (space group C 2/c, ) with the following unit cell dimensions: (1) Å, (6) Å, (2) Å, and (2). Besides, its structure was solved using 84860 independent reflections leading to . Electrical properties of the material were studied using impedance spectroscopic technique at different temperatures in the frequency range of 209 Hz to 5 MHz. Detailed analysis of the impedance spectrum suggested that the electrical properties of the material are strongly temperature-dependent. The Nyquist plots clearly showed the presence of bulk and grain boundary effect in the compound. |
url |
http://dx.doi.org/10.1155/2013/435462 |
work_keys_str_mv |
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