Cyclic voltammetry, square wave voltammetry, electrochemical impedance spectroscopy and colorimetric method for hydrogen peroxide detection based on chitosan/silver nanocomposite

In this paper, we demonstrate a promising method to fabricate a non-enzymatic stable, highly sensitive and selective hydrogen peroxide sensor based on a chitosan/silver nanoparticles (CS/AgNPs) hybrid. Using this composite, we elaborated both electrochemical and colorimetric sensors for hydrogen per...

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Bibliographic Details
Main Authors: Hoang V. Tran, Chinh D. Huynh, Hanh V. Tran, Benoit Piro
Format: Article
Language:English
Published: Elsevier 2018-05-01
Series:Arabian Journal of Chemistry
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535216301277
Description
Summary:In this paper, we demonstrate a promising method to fabricate a non-enzymatic stable, highly sensitive and selective hydrogen peroxide sensor based on a chitosan/silver nanoparticles (CS/AgNPs) hybrid. Using this composite, we elaborated both electrochemical and colorimetric sensors for hydrogen peroxide detection. The colorimetric sensor is based on a homogenous reaction which fades the color of CS/AgNPs solutions from red-orange to colorless depending on hydrogen peroxide concentration. For the electrochemical sensor, CS/AgNPs were immobilized on glassy carbon electrodes and hydrogen peroxide was measured using cyclic voltammetry, square wave voltammetry and electrochemical impedance spectroscopy. The response time is less than 10 s and the detection limit is 5 μM. Keywords: Spectrophotometric detection, Electrochemical impedance spectroscopy, Square wave voltammetry, Cyclic voltammetry, Chitosan/silver nanoparticles (CS/AgNPs) hybrid, Hydrogen peroxide
ISSN:1878-5352