Hydrothermally Processed Oxide Nanostructures and Their Lithium–ion Storage Properties

<p>Abstract</p> <p>Y- and Si-based oxide nanopowders were synthesized by a hydrothermal reaction of Y or Si powders with NaOH or LiOH aqueous solution. Nanoparticles with different morphology such as elongated nanospheres, flower-like nanoparticles and nanowires were produced by a...

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Bibliographic Details
Main Authors: Kim Yong-Jin, Wang Guoxiu, Ahn Jung-Ho
Format: Article
Language:English
Published: SpringerOpen 2010-01-01
Series:Nanoscale Research Letters
Subjects:
Online Access:http://dx.doi.org/10.1007/s11671-010-9722-y
Description
Summary:<p>Abstract</p> <p>Y- and Si-based oxide nanopowders were synthesized by a hydrothermal reaction of Y or Si powders with NaOH or LiOH aqueous solution. Nanoparticles with different morphology such as elongated nanospheres, flower-like nanoparticles and nanowires were produced by a control of processing parameters, in particular, the starting composition of solution. The preliminary result of electrochemical examination showed that the hydrothermally processed nanowires exhibit high initial capacities of Li-ion storage: 653 mAh/g for Y<sub>2</sub>O<sub>3</sub> nanowires as anode materials and 186 mAh/g for Li<sub>2</sub>Si<sub>2</sub>O<sub>5</sub> nanowires as cathode materials in a Li secondary cell. Compared to the powder with elongated sphere or flower-like shapes, the nanowires showed a higher Li-ion capacity and a better cycle property.</p>
ISSN:1931-7573
1556-276X