Bis(pyridine-κN){N2,N2′-[1,1′-(pyridine-2,6-diyl)diethylidyne]benzenesulfonohydrazonato-κ5O,N,N′,N′′,O′}nickel(II)
In the crystal structure of the title compound, [Ni(C21H19N5O4S2)(C5H5N)2], the metal center is seven-coordinate, with an approximate pentagonal-bipyramidal configuration. The Ni atom is chelated by a dianionic pentadentate Schiff base via the pyridine N atom, the two azomethine N atoms and the two...
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| Language: | English |
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International Union of Crystallography
2010-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809055639 |
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doaj-0a28901b784b46bfba16298c6c5b7d8a2020-11-25T02:19:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m129m12910.1107/S1600536809055639Bis(pyridine-κN){N2,N2′-[1,1′-(pyridine-2,6-diyl)diethylidyne]benzenesulfonohydrazonato-κ5O,N,N′,N′′,O′}nickel(II)Juahir YusnitaHapipah Mohd AliMahmood A. AbdullaWard T. RobinsonHamid KhalediIn the crystal structure of the title compound, [Ni(C21H19N5O4S2)(C5H5N)2], the metal center is seven-coordinate, with an approximate pentagonal-bipyramidal configuration. The Ni atom is chelated by a dianionic pentadentate Schiff base via the pyridine N atom, the two azomethine N atoms and the two sulfonyl O atoms. The latter coordinate to Ni at different distances, viz. 2.3337 (12) and 2.7988 (12) Å. Two apically coordinated pyridine molecules complete the seven-coordinate geometry. The dihedral angle between the two pyridine ring planes is 68.25 (6)°. http://scripts.iucr.org/cgi-bin/paper?S1600536809055639 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Juahir Yusnita Hapipah Mohd Ali Mahmood A. Abdulla Ward T. Robinson Hamid Khaledi |
| spellingShingle |
Juahir Yusnita Hapipah Mohd Ali Mahmood A. Abdulla Ward T. Robinson Hamid Khaledi Bis(pyridine-κN){N2,N2′-[1,1′-(pyridine-2,6-diyl)diethylidyne]benzenesulfonohydrazonato-κ5O,N,N′,N′′,O′}nickel(II) Acta Crystallographica Section E |
| author_facet |
Juahir Yusnita Hapipah Mohd Ali Mahmood A. Abdulla Ward T. Robinson Hamid Khaledi |
| author_sort |
Juahir Yusnita |
| title |
Bis(pyridine-κN){N2,N2′-[1,1′-(pyridine-2,6-diyl)diethylidyne]benzenesulfonohydrazonato-κ5O,N,N′,N′′,O′}nickel(II) |
| title_short |
Bis(pyridine-κN){N2,N2′-[1,1′-(pyridine-2,6-diyl)diethylidyne]benzenesulfonohydrazonato-κ5O,N,N′,N′′,O′}nickel(II) |
| title_full |
Bis(pyridine-κN){N2,N2′-[1,1′-(pyridine-2,6-diyl)diethylidyne]benzenesulfonohydrazonato-κ5O,N,N′,N′′,O′}nickel(II) |
| title_fullStr |
Bis(pyridine-κN){N2,N2′-[1,1′-(pyridine-2,6-diyl)diethylidyne]benzenesulfonohydrazonato-κ5O,N,N′,N′′,O′}nickel(II) |
| title_full_unstemmed |
Bis(pyridine-κN){N2,N2′-[1,1′-(pyridine-2,6-diyl)diethylidyne]benzenesulfonohydrazonato-κ5O,N,N′,N′′,O′}nickel(II) |
| title_sort |
bis(pyridine-κn){n2,n2′-[1,1′-(pyridine-2,6-diyl)diethylidyne]benzenesulfonohydrazonato-κ5o,n,n′,n′′,o′}nickel(ii) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2010-02-01 |
| description |
In the crystal structure of the title compound, [Ni(C21H19N5O4S2)(C5H5N)2], the metal center is seven-coordinate, with an approximate pentagonal-bipyramidal configuration. The Ni atom is chelated by a dianionic pentadentate Schiff base via the pyridine N atom, the two azomethine N atoms and the two sulfonyl O atoms. The latter coordinate to Ni at different distances, viz. 2.3337 (12) and 2.7988 (12) Å. Two apically coordinated pyridine molecules complete the seven-coordinate geometry. The dihedral angle between the two pyridine ring planes is 68.25 (6)°. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809055639 |
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