Crystal structure of (OC)5W(μ-dppe)W(CO)5

The centrosymmetric title complex, [μ-ethane-1,2-diylbis(diphenylphosphane)-κ2P:P′]bis[pentacarbonyltungsten(0)], [W2(C26H24P2)(CO)10], consists of two W(CO)5 moieties bridged by a bis(diphenylphosphanyl)ethane (dppe) ligand. The W0 atom has a slightly distorted octahedral coordination environment c...

Full description

Bibliographic Details
Main Authors:	Hannah F. Drake, Kraig A. Wheeler, Brian J. Bellott
Format:	Article
Language:	English
Published:	International Union of Crystallography 2016-10-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure group 6 carbonyl bridging dppe bimetallic
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989016013670

id	doaj-0a14bdc0b28c48d3ac6bbedf16f90f78
record_format	Article
spelling	doaj-0a14bdc0b28c48d3ac6bbedf16f90f782020-11-25T01:00:23ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-10-0172101383138510.1107/S2056989016013670vn2114Crystal structure of (OC)5W(μ-dppe)W(CO)5Hannah F. Drake0Kraig A. Wheeler1Brian J. Bellott2Department of Chemistry, Western Illinois University, Macomb, Illinois 61455, USADepartment of Chemistry, Eastern Illinois University, Charleston, Illinois, 61920, USADepartment of Chemistry, Western Illinois University, Macomb, Illinois 61455, USAThe centrosymmetric title complex, [μ-ethane-1,2-diylbis(diphenylphosphane)-κ2P:P′]bis[pentacarbonyltungsten(0)], [W2(C26H24P2)(CO)10], consists of two W(CO)5 moieties bridged by a bis(diphenylphosphanyl)ethane (dppe) ligand. The W0 atom has a slightly distorted octahedral coordination environment consisting of 5 carbonyl ligands and one P atom from the bridging dppe ligand with the nearest W0 atom 5.625 (5) Å away. The complex resides on a center of symmetry.http://scripts.iucr.org/cgi-bin/paper?S2056989016013670crystal structuregroup 6 carbonylbridging dppebimetallic
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Hannah F. Drake Kraig A. Wheeler Brian J. Bellott
spellingShingle	Hannah F. Drake Kraig A. Wheeler Brian J. Bellott Crystal structure of (OC)5W(μ-dppe)W(CO)5 Acta Crystallographica Section E: Crystallographic Communications crystal structure group 6 carbonyl bridging dppe bimetallic
author_facet	Hannah F. Drake Kraig A. Wheeler Brian J. Bellott
author_sort	Hannah F. Drake
title	Crystal structure of (OC)5W(μ-dppe)W(CO)5
title_short	Crystal structure of (OC)5W(μ-dppe)W(CO)5
title_full	Crystal structure of (OC)5W(μ-dppe)W(CO)5
title_fullStr	Crystal structure of (OC)5W(μ-dppe)W(CO)5
title_full_unstemmed	Crystal structure of (OC)5W(μ-dppe)W(CO)5
title_sort	crystal structure of (oc)5w(μ-dppe)w(co)5
publisher	International Union of Crystallography
series	Acta Crystallographica Section E: Crystallographic Communications
issn	2056-9890
publishDate	2016-10-01
description	The centrosymmetric title complex, [μ-ethane-1,2-diylbis(diphenylphosphane)-κ2P:P′]bis[pentacarbonyltungsten(0)], [W2(C26H24P2)(CO)10], consists of two W(CO)5 moieties bridged by a bis(diphenylphosphanyl)ethane (dppe) ligand. The W0 atom has a slightly distorted octahedral coordination environment consisting of 5 carbonyl ligands and one P atom from the bridging dppe ligand with the nearest W0 atom 5.625 (5) Å away. The complex resides on a center of symmetry.
topic	crystal structure group 6 carbonyl bridging dppe bimetallic
url	http://scripts.iucr.org/cgi-bin/paper?S2056989016013670
work_keys_str_mv	AT hannahfdrake crystalstructureofoc5wmdppewco5 AT kraigawheeler crystalstructureofoc5wmdppewco5 AT brianjbellott crystalstructureofoc5wmdppewco5
_version_	1725213816530141184

Crystal structure of (OC)5W(μ-dppe)W(CO)5

Similar Items