Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(II) tetrahydrate

Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(II) tetrahydrate

The asymmetric unit of the title complex, (C4H12N2)[Co(C7H3NO4)2]·4H2O, consists of one piperazinediium dication, one [Co(py-2,6-dc)2]2− dianion (where py-2,6-dc is pyridine-2,6-dicarboxylate) and four water molecules. The piperazinediium cation adopts a chair conformation...

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Main Authors: Akbar Raissi Shabari, Nazanin Ghoddoosi, Mehrdad Pourayoubi, Shahram Moradi
Format: Article
Language:English
Published: International Union of Crystallography 2011-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811023518
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spelling doaj-09fe0c81549f473da2bc35770fbbc0372020-11-24T21:29:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m985m98610.1107/S1600536811023518Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(II) tetrahydrateAkbar Raissi ShabariNazanin GhoddoosiMehrdad PourayoubiShahram MoradiThe asymmetric unit of the title complex, (C4H12N2)[Co(C7H3NO4)2]·4H2O, consists of one piperazinediium dication, one [Co(py-2,6-dc)2]2− dianion (where py-2,6-dc is pyridine-2,6-dicarboxylate) and four water molecules. The piperazinediium cation adopts a chair conformation and the CoII ion is six-coordinated in an N2O4 environment, having a distorted octahedral geometry. In the crystal, intermolecular O—H...O, N—H...O and weak C—H...O hydrogen bonds link the components, forming a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536811023518
collection DOAJ
language English
format Article
sources DOAJ
author Akbar Raissi Shabari
Nazanin Ghoddoosi
Mehrdad Pourayoubi
Shahram Moradi
spellingShingle Akbar Raissi Shabari
Nazanin Ghoddoosi
Mehrdad Pourayoubi
Shahram Moradi
Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(II) tetrahydrate
Acta Crystallographica Section E
author_facet Akbar Raissi Shabari
Nazanin Ghoddoosi
Mehrdad Pourayoubi
Shahram Moradi
author_sort Akbar Raissi Shabari
title Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(II) tetrahydrate
title_short Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(II) tetrahydrate
title_full Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(II) tetrahydrate
title_fullStr Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(II) tetrahydrate
title_full_unstemmed Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(II) tetrahydrate
title_sort piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ3o2,n,o6)cobaltate(ii) tetrahydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-07-01
description The asymmetric unit of the title complex, (C4H12N2)[Co(C7H3NO4)2]·4H2O, consists of one piperazinediium dication, one [Co(py-2,6-dc)2]2− dianion (where py-2,6-dc is pyridine-2,6-dicarboxylate) and four water molecules. The piperazinediium cation adopts a chair conformation and the CoII ion is six-coordinated in an N2O4 environment, having a distorted octahedral geometry. In the crystal, intermolecular O—H...O, N—H...O and weak C—H...O hydrogen bonds link the components, forming a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811023518
work_keys_str_mv AT akbarraissishabari piperazine14diiumbispyridine26dicarboxylatoamp9543o2no6cobaltateiitetrahydrate
AT nazaninghoddoosi piperazine14diiumbispyridine26dicarboxylatoamp9543o2no6cobaltateiitetrahydrate
AT mehrdadpourayoubi piperazine14diiumbispyridine26dicarboxylatoamp9543o2no6cobaltateiitetrahydrate
AT shahrammoradi piperazine14diiumbispyridine26dicarboxylatoamp9543o2no6cobaltateiitetrahydrate
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