Charge-Transfer Complexes Studied by Dynamic Force Spectroscopy

Charge-Transfer Complexes Studied by Dynamic Force Spectroscopy

In this paper, the strength and kinetics of two charge-transfer complexes, naphthol-methylviologen and pyrene-methylviologen, are studied using dynamic force spectroscopy. The dissociation rates indicate an enhanced stability of the pyrene-methylviologen complex, which agrees with its higher thermod...

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Main Authors: Jurriaan Huskens, Xi Zhang, Pascal Jonkheijm, Yiheng Zhang, Alberto Gomez-Casado, Arántzazu Gonzalez-Campo
Format: Article
Language:English
Published: MDPI AG 2013-03-01
Series:Polymers
Subjects:
charge-transfer complex
dynamic force spectroscopy
methyl viologen
naphthol
pyrene
kinetics
Online Access:http://www.mdpi.com/2073-4360/5/1/269
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spelling doaj-0958f4ff509f4eb3a5b27cf91619ef6e2020-11-24T21:04:05ZengMDPI AGPolymers2073-43602013-03-015126928310.3390/polym5010269Charge-Transfer Complexes Studied by Dynamic Force SpectroscopyJurriaan HuskensXi ZhangPascal JonkheijmYiheng ZhangAlberto Gomez-CasadoArántzazu Gonzalez-CampoIn this paper, the strength and kinetics of two charge-transfer complexes, naphthol-methylviologen and pyrene-methylviologen, are studied using dynamic force spectroscopy. The dissociation rates indicate an enhanced stability of the pyrene-methylviologen complex, which agrees with its higher thermodynamic stability compared to naphthol-methylviologen complex.http://www.mdpi.com/2073-4360/5/1/269charge-transfer complexdynamic force spectroscopymethyl viologennaphtholpyrenekinetics
collection DOAJ
language English
format Article
sources DOAJ
author Jurriaan Huskens
Xi Zhang
Pascal Jonkheijm
Yiheng Zhang
Alberto Gomez-Casado
Arántzazu Gonzalez-Campo
spellingShingle Jurriaan Huskens
Xi Zhang
Pascal Jonkheijm
Yiheng Zhang
Alberto Gomez-Casado
Arántzazu Gonzalez-Campo
Charge-Transfer Complexes Studied by Dynamic Force Spectroscopy
Polymers
charge-transfer complex
dynamic force spectroscopy
methyl viologen
naphthol
pyrene
kinetics
author_facet Jurriaan Huskens
Xi Zhang
Pascal Jonkheijm
Yiheng Zhang
Alberto Gomez-Casado
Arántzazu Gonzalez-Campo
author_sort Jurriaan Huskens
title Charge-Transfer Complexes Studied by Dynamic Force Spectroscopy
title_short Charge-Transfer Complexes Studied by Dynamic Force Spectroscopy
title_full Charge-Transfer Complexes Studied by Dynamic Force Spectroscopy
title_fullStr Charge-Transfer Complexes Studied by Dynamic Force Spectroscopy
title_full_unstemmed Charge-Transfer Complexes Studied by Dynamic Force Spectroscopy
title_sort charge-transfer complexes studied by dynamic force spectroscopy
publisher MDPI AG
series Polymers
issn 2073-4360
publishDate 2013-03-01
description In this paper, the strength and kinetics of two charge-transfer complexes, naphthol-methylviologen and pyrene-methylviologen, are studied using dynamic force spectroscopy. The dissociation rates indicate an enhanced stability of the pyrene-methylviologen complex, which agrees with its higher thermodynamic stability compared to naphthol-methylviologen complex.
topic charge-transfer complex
dynamic force spectroscopy
methyl viologen
naphthol
pyrene
kinetics
url http://www.mdpi.com/2073-4360/5/1/269
work_keys_str_mv AT jurriaanhuskens chargetransfercomplexesstudiedbydynamicforcespectroscopy
AT xizhang chargetransfercomplexesstudiedbydynamicforcespectroscopy
AT pascaljonkheijm chargetransfercomplexesstudiedbydynamicforcespectroscopy
AT yihengzhang chargetransfercomplexesstudiedbydynamicforcespectroscopy
AT albertogomezcasado chargetransfercomplexesstudiedbydynamicforcespectroscopy
AT arantzazugonzalezcampo chargetransfercomplexesstudiedbydynamicforcespectroscopy
_version_ 1716772036395663360

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