TiO2 Synthesis by Pechini Method and Application in Dye-Sensitized Solar Cells

• Main Authors: Gideã Taques Tractz, Bianca Vanjura Dias, Guilherme Arielo Rodrigues Maia, Paulo Rogério Pinto Rodrigues
• Format: Article
• Language: English
• Published: Universidade Federal de Mato Grosso do Sul 2021-06-01
• Series: Orbital: The Electronic Journal of Chemistry
• Subjects: gratzel cells; eis; pechini; pv cells
• Online Access: http://orbital.ufms.br/index.php/Chemistry/article/view/1446
• ISSN: 1984-6428

<p>Dye-sensitized solar cells (DSSC) are devices to solar energy conversion, which present low production costs and high photoelectrochemical stability. The aim of this study was to investigate the synthesis of TiO₂ by Pechini methodology, using C₁₂H₂₈O₄Ti and TiCl₃as precursors, and their application in solar cell sensitized by N719 dye. The characterization techniques employed were Scanning Electron Microscopy (SEM), UV-VIS Spectroscopy, X-ray diffraction (XRD), photochronoamperometry, j-V Curves and EIS plots. The results demonstrated a high crystallinity and surface area to particles obtained with C₁₂H₂₈O₄Ti as precursor. The highest photoconversion energy efficiency reached was to TiO₂ using C₁₂H₂₈O₄Ti with PCE= 4.17±0.13% with photoelectrochemical parameters of j_sc= 5.53 ±0.08, V_oc= 0.78±0.07 FF=0.58±0.05 and less resistive to charge transport with τ_e= 53 ms.</p><p> </p><p>DOI: <a href="http://dx.doi.org/10.17807/orbital.v13i2.1446">http://dx.doi.org/10.17807/orbital.v13i2.1446</a></p><p class="orbitalabstract"> </p>