Topological Analysis of Phase Equilibria in the Hg – H2O System

The analysis of the joint stability of phases and valence forms of mercury in the Hg – H2O system in the lg f O2 – 1/T coordinates for the temperature range from -50 to + 360°C was carried out by method of F. Schreinemakers. Analysis of equilibrium valence forms showed that for the composition of fl...

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Bibliographic Details
Main Authors: Alekhin Yury, Fiaizullina Renata, Bychkov Dmitry
Format: Article
Language:English
Published: EDP Sciences 2019-01-01
Series:E3S Web of Conferences
Online Access:https://www.e3s-conferences.org/articles/e3sconf/pdf/2019/24/e3sconf_wri-162018_06001.pdf
Description
Summary:The analysis of the joint stability of phases and valence forms of mercury in the Hg – H2O system in the lg f O2 – 1/T coordinates for the temperature range from -50 to + 360°C was carried out by method of F. Schreinemakers. Analysis of equilibrium valence forms showed that for the composition of fluid phases, the non-autonomy of the oxide film as a phase on the surface of liquid mercury is key.
ISSN:2267-1242