[N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O]dicyclohexyltin(IV)

[N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O]dicyclohexyltin(IV)

The environment at the SnIV atom in the title compound, [Sn(C6H11)2(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O—Sn—O angle is 155.97 (9)°. The p...

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Bibliographic Details
Main Authors: See Mun Lee, Hapipah Mohd Ali, Kong Mun Lo
Format: Article
Language:English
Published: International Union of Crystallography 2010-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810001145
Description
Summary:The environment at the SnIV atom in the title compound, [Sn(C6H11)2(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O—Sn—O angle is 155.97 (9)°. The presence of an intramolecular O—H...N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure.
ISSN:1600-5368

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