Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes

Two novel europium(III) complexes, a monomer and a homodimer, with 1-(4-chlorophenyl)-4,4,4-trifluoro-1,3-butanedione (Hcbtfa) and 5-chloro-1,10-phenanthroline (cphen) ligands, formulated as [Eu(cbtfa)3(cphen)] and [Eu2(cbtfa)4(cphen)2(CH3O)2], have been synthesized. Their structures have been eluci...

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Main Authors:	João P. Martins, Pablo Martín-Ramos, Pedro Chamorro-Posada, Pedro S. Pereira Silva, Jesús Martín-Gil, Salvador Hernández-Navarro, Manuela Ramos Silva
Format:	Article
Language:	English
Published:	Hindawi Limited 2015-01-01
Series:	Advances in Condensed Matter Physics
Online Access:	http://dx.doi.org/10.1155/2015/205047

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spelling	doaj-08977fd5bfb6430584816cf8e3a477532020-11-25T01:11:13ZengHindawi LimitedAdvances in Condensed Matter Physics1687-81081687-81242015-01-01201510.1155/2015/205047205047Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate ComplexesJoão P. Martins0Pablo Martín-Ramos1Pedro Chamorro-Posada2Pedro S. Pereira Silva3Jesús Martín-Gil4Salvador Hernández-Navarro5Manuela Ramos Silva6CFisUC, Department of Physics, University of Coimbra, Rua Larga, 3004-516 Coimbra, PortugalCFisUC, Department of Physics, University of Coimbra, Rua Larga, 3004-516 Coimbra, PortugalSignal Theory, Communications and Telematics Engineering Department, ETSIT, University of Valladolid, Campus Miguel Delibes, Paseo Belén 15, 47011 Valladolid, SpainCFisUC, Department of Physics, University of Coimbra, Rua Larga, 3004-516 Coimbra, PortugalAdvanced Materials Laboratory, ETSIIAA, University of Valladolid, Avenida de Madrid 44, 34004 Palencia, SpainAdvanced Materials Laboratory, ETSIIAA, University of Valladolid, Avenida de Madrid 44, 34004 Palencia, SpainCFisUC, Department of Physics, University of Coimbra, Rua Larga, 3004-516 Coimbra, PortugalTwo novel europium(III) complexes, a monomer and a homodimer, with 1-(4-chlorophenyl)-4,4,4-trifluoro-1,3-butanedione (Hcbtfa) and 5-chloro-1,10-phenanthroline (cphen) ligands, formulated as [Eu(cbtfa)3(cphen)] and [Eu2(cbtfa)4(cphen)2(CH3O)2], have been synthesized. Their structures have been elucidated by X-ray diffraction and their absorption and emission properties have been studied in the solid state. The experimental data has then been used to test the recently released LUMPAC software, a promising tool which can facilitate the design of more efficient lanthanide light-conversion molecular devices by combining ground state geometry, excited state energy, and luminescent properties calculations.http://dx.doi.org/10.1155/2015/205047
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	João P. Martins Pablo Martín-Ramos Pedro Chamorro-Posada Pedro S. Pereira Silva Jesús Martín-Gil Salvador Hernández-Navarro Manuela Ramos Silva
spellingShingle	João P. Martins Pablo Martín-Ramos Pedro Chamorro-Posada Pedro S. Pereira Silva Jesús Martín-Gil Salvador Hernández-Navarro Manuela Ramos Silva Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes Advances in Condensed Matter Physics
author_facet	João P. Martins Pablo Martín-Ramos Pedro Chamorro-Posada Pedro S. Pereira Silva Jesús Martín-Gil Salvador Hernández-Navarro Manuela Ramos Silva
author_sort	João P. Martins
title	Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes
title_short	Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes
title_full	Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes
title_fullStr	Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes
title_full_unstemmed	Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes
title_sort	experimental and theoretical studies on the structure and photoluminescent properties of new mononuclear and homodinuclear europium(iii) β-diketonate complexes
publisher	Hindawi Limited
series	Advances in Condensed Matter Physics
issn	1687-8108 1687-8124
publishDate	2015-01-01
description	Two novel europium(III) complexes, a monomer and a homodimer, with 1-(4-chlorophenyl)-4,4,4-trifluoro-1,3-butanedione (Hcbtfa) and 5-chloro-1,10-phenanthroline (cphen) ligands, formulated as [Eu(cbtfa)3(cphen)] and [Eu2(cbtfa)4(cphen)2(CH3O)2], have been synthesized. Their structures have been elucidated by X-ray diffraction and their absorption and emission properties have been studied in the solid state. The experimental data has then been used to test the recently released LUMPAC software, a promising tool which can facilitate the design of more efficient lanthanide light-conversion molecular devices by combining ground state geometry, excited state energy, and luminescent properties calculations.
url	http://dx.doi.org/10.1155/2015/205047
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Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes

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