Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins – mechanistic considerations
We have developed a new effective route for obtaining (E)-vinyl-substituted silatranes via ruthenium-catalyzed silylative coupling of 1-allylsilatrane with olefins. Experimental research allowed us also to propose the mechanism of the process based on stoichiometric reactions.
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2020-03-01
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| Series: | Heterocyclic Communications |
| Online Access: | http://www.degruyter.com/view/j/hc.2020.26.issue-1/hc-2020-0006/hc-2020-0006.xml?format=INT |