Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins – mechanistic considerations

We have developed a new effective route for obtaining (E)-vinyl-substituted silatranes via ruthenium-catalyzed silylative coupling of 1-allylsilatrane with olefins. Experimental research allowed us also to propose the mechanism of the process based on stoichiometric reactions.

Bibliographic Details
Main Authors:	Sztorch Bogna, Frąckowiak Dawid, Marciniec Bogdan
Format:	Article
Language:	English
Published:	De Gruyter 2020-03-01
Series:	Heterocyclic Communications
Online Access:	http://www.degruyter.com/view/j/hc.2020.26.issue-1/hc-2020-0006/hc-2020-0006.xml?format=INT

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spelling	doaj-08374f86dcaa47d7b2847edd8f42e2b62021-02-28T21:53:15ZengDe GruyterHeterocyclic Communications2191-01972020-03-01261333610.1515/hc-2020-0006hc-2020-0006Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins – mechanistic considerationsSztorch Bogna0Frąckowiak Dawid1Marciniec Bogdan2Adam Mickiewicz University in Poznań, Center for Advanced Technology, Uniwersytetu Poznańskiego 10, 61-614Poznań, PolandCenter for Advanced Technology, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 10, 61-614Poznań, PolandAdam Mickiewicz University in Poznań, Faculty of Chemistry, Uniwersytetu Poznańskiego 8, 61-614Poznań, PolandWe have developed a new effective route for obtaining (E)-vinyl-substituted silatranes via ruthenium-catalyzed silylative coupling of 1-allylsilatrane with olefins. Experimental research allowed us also to propose the mechanism of the process based on stoichiometric reactions.http://www.degruyter.com/view/j/hc.2020.26.issue-1/hc-2020-0006/hc-2020-0006.xml?format=INT
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Sztorch Bogna Frąckowiak Dawid Marciniec Bogdan
spellingShingle	Sztorch Bogna Frąckowiak Dawid Marciniec Bogdan Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins – mechanistic considerations Heterocyclic Communications
author_facet	Sztorch Bogna Frąckowiak Dawid Marciniec Bogdan
author_sort	Sztorch Bogna
title	Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins – mechanistic considerations
title_short	Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins – mechanistic considerations
title_full	Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins – mechanistic considerations
title_fullStr	Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins – mechanistic considerations
title_full_unstemmed	Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins – mechanistic considerations
title_sort	reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins – mechanistic considerations
publisher	De Gruyter
series	Heterocyclic Communications
issn	2191-0197
publishDate	2020-03-01
description	We have developed a new effective route for obtaining (E)-vinyl-substituted silatranes via ruthenium-catalyzed silylative coupling of 1-allylsilatrane with olefins. Experimental research allowed us also to propose the mechanism of the process based on stoichiometric reactions.
url	http://www.degruyter.com/view/j/hc.2020.26.issue-1/hc-2020-0006/hc-2020-0006.xml?format=INT
work_keys_str_mv	AT sztorchbogna reactivityof1allylsilatraneinrutheniumcatalyzedsilylativecouplingwitholefinsmechanisticconsiderations AT frackowiakdawid reactivityof1allylsilatraneinrutheniumcatalyzedsilylativecouplingwitholefinsmechanisticconsiderations AT marciniecbogdan reactivityof1allylsilatraneinrutheniumcatalyzedsilylativecouplingwitholefinsmechanisticconsiderations
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Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins – mechanistic considerations

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