Transfer Hydrogenation from 2-propanol to Acetophenone Catalyzed by [RuCl<sub>2</sub>(η<sup>6</sup>-arene)P] (P = monophosphine) and [Rh(PP)<sub>2</sub>]X (PP = diphosphine, X = Cl<sup>−</sup>, BF<sub>4</sub><sup>−</sup>) Complexes

Transfer Hydrogenation from 2-propanol to Acetophenone Catalyzed by [RuCl<sub>2</sub>(η<sup>6</sup>-arene)P] (P = monophosphine) and [Rh(PP)<sub>2</sub>]X (PP = diphosphine, X = Cl<sup>−</sup>, BF<sub>4</sub><sup>−</sup>) Complexes

The reduction of ketones through homogeneous transfer hydrogenation catalyzed by transition metals is one of the most important routes for obtaining alcohols from carbonyl compounds. The interest of this method increases when opportune catalytic precursors are able to perform the transformation in a...

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Bibliographic Details
Main Authors: Alberto Mannu, Arnald Grabulosa, Salvatore Baldino
Format: Article
Language:English
Published: MDPI AG 2020-02-01
Series:Catalysts
Subjects:
transfer hydrogenation
ruthenium
rhodium
catalysis
ketone reduction
Online Access:https://www.mdpi.com/2073-4344/10/2/162

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