Comprehensive GC–FID, GC–MS and FT-IR spectroscopic analysis of the volatile aroma constituents of Artemisia indica and Artemisia vestita essential oils

In the current study, the leaf volatile constituents of the essential oils of Artemisia indica Willd. and Artemisia vestita Wall were studied using a combination of capillary GC–FID, GC–MS and FT-IR (Fourier-Transform Infra-Red) analytical techniques. The analysis led to the identification of 42 com...

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Main Authors: Manzoor A. Rather, Bilal A. Dar, Wajahat A. Shah, Anil Prabhakar, Kushal Bindu, Javid A. Banday, Mushtaq A. Qurishi
Format: Article
Language:English
Published: Elsevier 2017-05-01
Series:Arabian Journal of Chemistry
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535214000938
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spelling doaj-07695307482741e4b819b3e17c67a6142020-11-24T22:34:41ZengElsevierArabian Journal of Chemistry1878-53522017-05-0110S2S3798S380310.1016/j.arabjc.2014.05.017Comprehensive GC–FID, GC–MS and FT-IR spectroscopic analysis of the volatile aroma constituents of Artemisia indica and Artemisia vestita essential oilsManzoor A. Rather0Bilal A. Dar1Wajahat A. Shah2Anil Prabhakar3Kushal Bindu4Javid A. Banday5Mushtaq A. Qurishi6Department of Chemistry, University of Kashmir, Srinagar 190006, IndiaMedicinal Chemistry Division, Indian Institute of Integrative Medicine (CSIR), Srinagar 190005, IndiaDepartment of Chemistry, University of Kashmir, Srinagar 190006, IndiaInstrumentation Division, Indian Institute of Integrative Medicine, Jammu, IndiaInstrumentation Division, Indian Institute of Integrative Medicine, Jammu, IndiaDepartment of Chemistry, National Institute of Technology (NIT), Srinagar, IndiaDepartment of Chemistry, University of Kashmir, Srinagar 190006, IndiaIn the current study, the leaf volatile constituents of the essential oils of Artemisia indica Willd. and Artemisia vestita Wall were studied using a combination of capillary GC–FID, GC–MS and FT-IR (Fourier-Transform Infra-Red) analytical techniques. The analysis led to the identification of 42 compounds in the essential oil of A. indica, representing 96.6% of the essential oil and the major components were found to be artemisia ketone (42.1%), germacrene D (8.6%), borneol (6.1%) and cis-chrysanthenyl acetate (4.8%). The essential oil was dominated by the presence of oxygenated monoterpenes constituting 65.2% of the total oil composition followed by sesquiterpene hydrocarbons and monoterpene hydrocarbons constituting 15.7% and 10.7%, respectively of the total oil composition. The essential oil composition of A. vestita was found to contain a total of 18 components representing 94.2% of the total oil composition. The principal components were found to be 1,8-cineole (46.8%), (E)-citral (13.7%), limonene (9.8%), α-phellandrene (6.4%), camphor (5.0%), (Z) and (E)-thujones (3.0% each). Oxygenated monoterpenes were the dominant group of terpenes in the essential oil constituting 73.1% of the total oil composition followed by monoterpene hydrocarbons (17.3%). The results of the current study reveal remarkable differences in the essential oil compositions of these two Artemisia species already reported in the literature from other parts of the globe.http://www.sciencedirect.com/science/article/pii/S1878535214000938Artemisia indica WilldArtemisia vestita WallEssential oilGC–MSArtemisia ketone1,8-Cineole
collection DOAJ
language English
format Article
sources DOAJ
author Manzoor A. Rather
Bilal A. Dar
Wajahat A. Shah
Anil Prabhakar
Kushal Bindu
Javid A. Banday
Mushtaq A. Qurishi
spellingShingle Manzoor A. Rather
Bilal A. Dar
Wajahat A. Shah
Anil Prabhakar
Kushal Bindu
Javid A. Banday
Mushtaq A. Qurishi
Comprehensive GC–FID, GC–MS and FT-IR spectroscopic analysis of the volatile aroma constituents of Artemisia indica and Artemisia vestita essential oils
Arabian Journal of Chemistry
Artemisia indica Willd
Artemisia vestita Wall
Essential oil
GC–MS
Artemisia ketone
1,8-Cineole
author_facet Manzoor A. Rather
Bilal A. Dar
Wajahat A. Shah
Anil Prabhakar
Kushal Bindu
Javid A. Banday
Mushtaq A. Qurishi
author_sort Manzoor A. Rather
title Comprehensive GC–FID, GC–MS and FT-IR spectroscopic analysis of the volatile aroma constituents of Artemisia indica and Artemisia vestita essential oils
title_short Comprehensive GC–FID, GC–MS and FT-IR spectroscopic analysis of the volatile aroma constituents of Artemisia indica and Artemisia vestita essential oils
title_full Comprehensive GC–FID, GC–MS and FT-IR spectroscopic analysis of the volatile aroma constituents of Artemisia indica and Artemisia vestita essential oils
title_fullStr Comprehensive GC–FID, GC–MS and FT-IR spectroscopic analysis of the volatile aroma constituents of Artemisia indica and Artemisia vestita essential oils
title_full_unstemmed Comprehensive GC–FID, GC–MS and FT-IR spectroscopic analysis of the volatile aroma constituents of Artemisia indica and Artemisia vestita essential oils
title_sort comprehensive gc–fid, gc–ms and ft-ir spectroscopic analysis of the volatile aroma constituents of artemisia indica and artemisia vestita essential oils
publisher Elsevier
series Arabian Journal of Chemistry
issn 1878-5352
publishDate 2017-05-01
description In the current study, the leaf volatile constituents of the essential oils of Artemisia indica Willd. and Artemisia vestita Wall were studied using a combination of capillary GC–FID, GC–MS and FT-IR (Fourier-Transform Infra-Red) analytical techniques. The analysis led to the identification of 42 compounds in the essential oil of A. indica, representing 96.6% of the essential oil and the major components were found to be artemisia ketone (42.1%), germacrene D (8.6%), borneol (6.1%) and cis-chrysanthenyl acetate (4.8%). The essential oil was dominated by the presence of oxygenated monoterpenes constituting 65.2% of the total oil composition followed by sesquiterpene hydrocarbons and monoterpene hydrocarbons constituting 15.7% and 10.7%, respectively of the total oil composition. The essential oil composition of A. vestita was found to contain a total of 18 components representing 94.2% of the total oil composition. The principal components were found to be 1,8-cineole (46.8%), (E)-citral (13.7%), limonene (9.8%), α-phellandrene (6.4%), camphor (5.0%), (Z) and (E)-thujones (3.0% each). Oxygenated monoterpenes were the dominant group of terpenes in the essential oil constituting 73.1% of the total oil composition followed by monoterpene hydrocarbons (17.3%). The results of the current study reveal remarkable differences in the essential oil compositions of these two Artemisia species already reported in the literature from other parts of the globe.
topic Artemisia indica Willd
Artemisia vestita Wall
Essential oil
GC–MS
Artemisia ketone
1,8-Cineole
url http://www.sciencedirect.com/science/article/pii/S1878535214000938
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