Bis(tetraphenylphosphonium) bis[N-(trifluoromethylsulfonyl)dithiocarbimato(2−)-κ2S,S′]zincate(II)

Bis(tetraphenylphosphonium) bis[N-(trifluoromethylsulfonyl)dithiocarbimato(2−)-κ2S,S′]zincate(II)

The title salt, (C24H20P)2[Zn(C2F3NO2S3)2], consists of a complex dianion and two tetraphenylphosphonium cations. The ZnII ion displays a distorted tetrahedral coordination environment with four S atoms from two S,S′-chelated N-(trifluoromethylsulfonyl)dithiocarbimate anions. In the cr...

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Bibliographic Details
Main Authors: Paula S. Pinto, Mayura M. M. Rubinger, Silvana Guilardi, Drielly A. Paixão, Marcelo R. L. Oliveira
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681105207X
Description
Summary:The title salt, (C24H20P)2[Zn(C2F3NO2S3)2], consists of a complex dianion and two tetraphenylphosphonium cations. The ZnII ion displays a distorted tetrahedral coordination environment with four S atoms from two S,S′-chelated N-(trifluoromethylsulfonyl)dithiocarbimate anions. In the crystal, besides the ionic interaction of the oppositely charged ions, intermolecular C—H...O interactions between cations and anions are observed. One of the cations interacts with an inversion-related equivalent by π–π stacking between phenyl rings, with a centroid–centroid distance of 3.932 (4) Å.
ISSN:1600-5368

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