Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene

Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene

A new strategy for the synthesis of 2-substituted tetraphenylenes through a transition-metal-catalyzed derivatization has been developed. Three types of functionalities, including OAc, X (Cl, Br, I) and carbonyl, were introduced onto tetraphenylene, which allows the easy access to a variety of monos...

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Main Authors: Shulei Pan, Hang Jiang, Yanghui Zhang, Yu Zhang, Dushen Chen
Format: Article
Language:English
Published: Beilstein-Institut 2016-06-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
acetoxylation
carbonylation
halogenation
tetraphenylene
transition metal
Online Access:https://doi.org/10.3762/bjoc.12.122
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spelling doaj-06ce851890c54703908cfb75bcc817fb2021-02-02T08:28:34ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972016-06-011211302130810.3762/bjoc.12.1221860-5397-12-122Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenyleneShulei Pan0Hang Jiang1Yanghui Zhang2Yu Zhang3Dushen Chen4Department of Chemistry, and Shanghai Key Lab of Chemical Assessment and Sustainability, Tongji University, 1239 Siping Road, Shanghai, 200092, P. R. ChinaDepartment of Chemistry, and Shanghai Key Lab of Chemical Assessment and Sustainability, Tongji University, 1239 Siping Road, Shanghai, 200092, P. R. ChinaDepartment of Chemistry, and Shanghai Key Lab of Chemical Assessment and Sustainability, Tongji University, 1239 Siping Road, Shanghai, 200092, P. R. ChinaDepartment of Chemistry, and Shanghai Key Lab of Chemical Assessment and Sustainability, Tongji University, 1239 Siping Road, Shanghai, 200092, P. R. ChinaDepartment of Chemistry, and Shanghai Key Lab of Chemical Assessment and Sustainability, Tongji University, 1239 Siping Road, Shanghai, 200092, P. R. ChinaA new strategy for the synthesis of 2-substituted tetraphenylenes through a transition-metal-catalyzed derivatization has been developed. Three types of functionalities, including OAc, X (Cl, Br, I) and carbonyl, were introduced onto tetraphenylene, which allows the easy access to a variety of monosubstituted tetraphenylenes. These reactions could accelerate research on the properties and application of tetraphenylene derivatives.https://doi.org/10.3762/bjoc.12.122acetoxylationcarbonylationhalogenationtetraphenylenetransition metal
collection DOAJ
language English
format Article
sources DOAJ
author Shulei Pan
Hang Jiang
Yanghui Zhang
Yu Zhang
Dushen Chen
spellingShingle Shulei Pan
Hang Jiang
Yanghui Zhang
Yu Zhang
Dushen Chen
Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene
Beilstein Journal of Organic Chemistry
acetoxylation
carbonylation
halogenation
tetraphenylene
transition metal
author_facet Shulei Pan
Hang Jiang
Yanghui Zhang
Yu Zhang
Dushen Chen
author_sort Shulei Pan
title Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene
title_short Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene
title_full Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene
title_fullStr Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene
title_full_unstemmed Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene
title_sort synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene
publisher Beilstein-Institut
series Beilstein Journal of Organic Chemistry
issn 1860-5397
publishDate 2016-06-01
description A new strategy for the synthesis of 2-substituted tetraphenylenes through a transition-metal-catalyzed derivatization has been developed. Three types of functionalities, including OAc, X (Cl, Br, I) and carbonyl, were introduced onto tetraphenylene, which allows the easy access to a variety of monosubstituted tetraphenylenes. These reactions could accelerate research on the properties and application of tetraphenylene derivatives.
topic acetoxylation
carbonylation
halogenation
tetraphenylene
transition metal
url https://doi.org/10.3762/bjoc.12.122
work_keys_str_mv AT shuleipan synthesisof2substitutedtetraphenylenesviatransitionmetalcatalyzedderivatizationoftetraphenylene
AT hangjiang synthesisof2substitutedtetraphenylenesviatransitionmetalcatalyzedderivatizationoftetraphenylene
AT yanghuizhang synthesisof2substitutedtetraphenylenesviatransitionmetalcatalyzedderivatizationoftetraphenylene
AT yuzhang synthesisof2substitutedtetraphenylenesviatransitionmetalcatalyzedderivatizationoftetraphenylene
AT dushenchen synthesisof2substitutedtetraphenylenesviatransitionmetalcatalyzedderivatizationoftetraphenylene
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