Lead activity in Pb-Sb-Bi alloys

The present work is devoted to the study of lead thermodynamic activity in the Pb-Sb-Bi alloys. The method for EMF measurements of the concentration cell: (–)Pb|KCl-PbCl2¦¦KCl-PbCl2|Pb-(Sb-Bi)(+) was used. The obtained concentration dependences of the galvanic cell EMF are described by linear equati...

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Main Authors: A. S. Kholkina, P. A. Arkhipov, Yu. P. Zaikov
Format: Article
Language:English
Published: Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina 2014-11-01
Series:Chimica Techno Acta
Subjects:
Online Access:https://journals.urfu.ru/index.php/chimtech/article/view/693
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spelling doaj-06cdbd8c3d1640148b33430c054cc8442020-11-25T00:55:13ZengUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina Chimica Techno Acta2409-56132411-14142014-11-0111333710.15826/chimtech.2014.1.1.6931009Lead activity in Pb-Sb-Bi alloysA. S. Kholkina0P. A. Arkhipov1Yu. P. Zaikov2Institute of High-temperature Electrochemistry UB RAS, EkaterinburgInstitute of High-temperature Electrochemistry UB RAS, EkaterinburgInstitute of High-temperature Electrochemistry UB RAS, EkaterinburgThe present work is devoted to the study of lead thermodynamic activity in the Pb-Sb-Bi alloys. The method for EMF measurements of the concentration cell: (–)Pb|KCl-PbCl2¦¦KCl-PbCl2|Pb-(Sb-Bi)(+) was used. The obtained concentration dependences of the galvanic cell EMF are described by linear equations. The lead activity in the ternary liquid-metal alloy demonstrates insignificant negative deviations from the behavior of ideal solutions.https://journals.urfu.ru/index.php/chimtech/article/view/693термодинамическая активность свинцатройные сплавыгальванический элементсурьмависмут
collection DOAJ
language English
format Article
sources DOAJ
author A. S. Kholkina
P. A. Arkhipov
Yu. P. Zaikov
spellingShingle A. S. Kholkina
P. A. Arkhipov
Yu. P. Zaikov
Lead activity in Pb-Sb-Bi alloys
Chimica Techno Acta
термодинамическая активность свинца
тройные сплавы
гальванический элемент
сурьма
висмут
author_facet A. S. Kholkina
P. A. Arkhipov
Yu. P. Zaikov
author_sort A. S. Kholkina
title Lead activity in Pb-Sb-Bi alloys
title_short Lead activity in Pb-Sb-Bi alloys
title_full Lead activity in Pb-Sb-Bi alloys
title_fullStr Lead activity in Pb-Sb-Bi alloys
title_full_unstemmed Lead activity in Pb-Sb-Bi alloys
title_sort lead activity in pb-sb-bi alloys
publisher Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
series Chimica Techno Acta
issn 2409-5613
2411-1414
publishDate 2014-11-01
description The present work is devoted to the study of lead thermodynamic activity in the Pb-Sb-Bi alloys. The method for EMF measurements of the concentration cell: (–)Pb|KCl-PbCl2¦¦KCl-PbCl2|Pb-(Sb-Bi)(+) was used. The obtained concentration dependences of the galvanic cell EMF are described by linear equations. The lead activity in the ternary liquid-metal alloy demonstrates insignificant negative deviations from the behavior of ideal solutions.
topic термодинамическая активность свинца
тройные сплавы
гальванический элемент
сурьма
висмут
url https://journals.urfu.ru/index.php/chimtech/article/view/693
work_keys_str_mv AT askholkina leadactivityinpbsbbialloys
AT paarkhipov leadactivityinpbsbbialloys
AT yupzaikov leadactivityinpbsbbialloys
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