catena-Poly[[bis(nitrato-κ2O,O′)barium]-bis(μ-l-histidine-κ3O,O′:O]

In the polymeric title compound, [Ba(NO3)2(C6H9N3O2)2]n, the BaII atom is located on a crystallographic twofold axis and is coordinated by ten O atoms. Six are derived from two zwitterionic l-histidine molecules that simultaneously chelate one BaII atom and bridge to another. The remaining four O at...

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Bibliographic Details
Main Authors: P. Arularasan, G. Chakkaravarthi, R. Mohan
Format: Article
Language:English
Published: International Union of Crystallography 2013-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813027402
Description
Summary:In the polymeric title compound, [Ba(NO3)2(C6H9N3O2)2]n, the BaII atom is located on a crystallographic twofold axis and is coordinated by ten O atoms. Six are derived from two zwitterionic l-histidine molecules that simultaneously chelate one BaII atom and bridge to another. The remaining four O atoms are derived from two chelating nitrates. The molecules assemble to form a chain along [010]. In the crystal, chains are linked via N—H...O and N—H...N hydrogen bonds, generating a three-dimensional network.
ISSN:1600-5368