Shear-induced ordering in liquid microjets seen by x-ray cross correlation analysis

We applied shear to a silica nanoparticle dispersion in a microfluidic jet device and observed direction-dependent structure along and across the flow direction. The asymmetries of the diffraction patterns were evaluated by x-ray cross correlation analysis. For different Rayleigh nozzle sizes and sh...

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Bibliographic Details
Main Authors: V. Markmann, M. Dartsch, J. Valerio, L. Frenzel, I. Lokteva, M. Walther, F. Westermeier, G. Grübel, F. Lehmkühler
Format: Article
Language:English
Published: AIP Publishing LLC and ACA 2020-09-01
Series:Structural Dynamics
Online Access:http://dx.doi.org/10.1063/4.0000038
Description
Summary:We applied shear to a silica nanoparticle dispersion in a microfluidic jet device and observed direction-dependent structure along and across the flow direction. The asymmetries of the diffraction patterns were evaluated by x-ray cross correlation analysis. For different Rayleigh nozzle sizes and shapes, we measured the decay of the shear-induced ordering after the cessation of the shear. At large tube sizes and small shear rates, the characteristic times of the decay become longer, but Péclet-weighted times do not scale linearly with Péclet numbers. By modeling particle distributions with the corresponding diffraction patterns and comparing measured shape asymmetry to simulations, we determined the variation of volume fraction over the azimuthal angle for the maximum ordered state in the jet.
ISSN:2329-7778