Metal–Dithiolene Bonding Contributions to Pyranopterin Molybdenum Enzyme Reactivity
Here we highlight past work on metal−dithiolene interactions and how the unique electronic structure of the metal−dithiolene unit contributes to both the oxidative and reductive half reactions in pyranopterin molybdenum and tungsten enzymes. The metallodithiolene electronic struc...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2020-03-01
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| Series: | Inorganics |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2304-6740/8/3/19 |