Zirconium-bearing accessory minerals in UK Paleogene granites: textural, compositional, and paragenetic relationships

<p>The mineral occurrences, parageneses, textures, and compositions of Zr-bearing accessory minerals in a suite of UK Paleogene granites from Scotland and Northern Ireland are described. Baddeleyite, zirconolite, and zircon, in that sequence, formed in hornblende <span class="inline-fo...

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Bibliographic Details
Main Authors: H. E. Belkin, R. Macdonald
Format: Article
Language:English
Published: Copernicus Publications 2021-09-01
Series:European Journal of Mineralogy
Online Access:https://ejm.copernicus.org/articles/33/537/2021/ejm-33-537-2021.pdf
Description
Summary:<p>The mineral occurrences, parageneses, textures, and compositions of Zr-bearing accessory minerals in a suite of UK Paleogene granites from Scotland and Northern Ireland are described. Baddeleyite, zirconolite, and zircon, in that sequence, formed in hornblende <span class="inline-formula">+</span> biotite granites (type 1) and hedenbergite–fayalite granites (type 2). The peralkaline microgranite (type 3) of Ailsa Craig contains zircon, dalyite, a eudialyte-group mineral, a fibrous phase which is possibly lemoynite, and Zr-bearing aegirine. Hydrothermal zircon is also present in all three granite types and documents the transition from a silicate-melt environment to an incompatible element-rich aqueous-dominated fluid. No textures indicative of inherited zircon were observed. The minerals crystallized in stages from magmatic through late-magmatic to hydrothermal. The zirconolite and eudialyte-group mineral are notably Y<span class="inline-formula">+</span>REE-rich (REE signifies rare earth element). The crystallization sequence of the minerals may have been related to the activities of Si and Ca, to melt peralkalinity, and to local disequilibrium.</p>
ISSN:0935-1221
1617-4011