[2,2-Bis(diphenylphosphanyl)propane-κ2P,P′]tetracarbonylchromium(0) dichloromethane monosolvate

[2,2-Bis(diphenylphosphanyl)propane-κ2P,P′]tetracarbonylchromium(0) dichloromethane monosolvate

The title compound, [Cr(C27H26P2)(CO)4]·CH2Cl2, was obtained by the reaction of Ph2PCMe2PPh2 with Cr(CO)6 in refluxing toluene by substitution of two carbonyl ligands. The CrC4P2 coordination geometry at the Cr atom is distorted octahedral, with a P—Cr—P bite...

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Bibliographic Details
Main Authors: Normen Peulecke, Stephan Peitz, Bernd H. Müller, Anke Spannenberg, Uwe Rosenthal
Format: Article
Language:English
Published: International Union of Crystallography 2010-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810043692
Description
Summary:The title compound, [Cr(C27H26P2)(CO)4]·CH2Cl2, was obtained by the reaction of Ph2PCMe2PPh2 with Cr(CO)6 in refluxing toluene by substitution of two carbonyl ligands. The CrC4P2 coordination geometry at the Cr atom is distorted octahedral, with a P—Cr—P bite angle of 70.27 (2)°.
ISSN:1600-5368

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