Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-olato-κ4N2,O:O,N2′]bis[(acetato-κ2O,O′)nickel(II)] methanol hemisolvate

Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-olato-κ4N2,O:O,N2′]bis[(acetato-κ2O,O′)nickel(II)] methanol hemisolvate

In the title complex, [Ni2(C13H11F2N6O)2(C2H3O2)2]·0.5CH3OH, there are two half-molecules in the asymmetric unit. The two centrosymmetrically related NiII atoms, each attached to an acetate ligand, are linked by two fluconazole ligands. Each NiII atom is six-coordinated in a distorted o...

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Main Authors: Feng Zhang, Fei-Long Hu, Zhong-Jing Huang, Ji-Chang Zhuang, Yue Zhuang
Format: Article
Language:English
Published: International Union of Crystallography 2010-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680905377X
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spelling doaj-057542eed94e4b57a03a382c39ce26382020-11-25T00:52:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-01-01661m75m7610.1107/S160053680905377XBis[μ-2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-olato-κ4N2,O:O,N2′]bis[(acetato-κ2O,O′)nickel(II)] methanol hemisolvateFeng ZhangFei-Long HuZhong-Jing HuangJi-Chang ZhuangYue ZhuangIn the title complex, [Ni2(C13H11F2N6O)2(C2H3O2)2]·0.5CH3OH, there are two half-molecules in the asymmetric unit. The two centrosymmetrically related NiII atoms, each attached to an acetate ligand, are linked by two fluconazole ligands. Each NiII atom is six-coordinated in a distorted octahedral geometry by two N atoms of the triazole groups and two bridging O atoms from two different fluconazole ligands and two O atoms from a chelating acetate ligand. In the crystal structure, the half-occupied methanol solvent molecule is linked to a triazole group via an O—H...N hydrogen bond. http://scripts.iucr.org/cgi-bin/paper?S160053680905377X
collection DOAJ
language English
format Article
sources DOAJ
author Feng Zhang
Fei-Long Hu
Zhong-Jing Huang
Ji-Chang Zhuang
Yue Zhuang
spellingShingle Feng Zhang
Fei-Long Hu
Zhong-Jing Huang
Ji-Chang Zhuang
Yue Zhuang
Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-olato-κ4N2,O:O,N2′]bis[(acetato-κ2O,O′)nickel(II)] methanol hemisolvate
Acta Crystallographica Section E
author_facet Feng Zhang
Fei-Long Hu
Zhong-Jing Huang
Ji-Chang Zhuang
Yue Zhuang
author_sort Feng Zhang
title Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-olato-κ4N2,O:O,N2′]bis[(acetato-κ2O,O′)nickel(II)] methanol hemisolvate
title_short Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-olato-κ4N2,O:O,N2′]bis[(acetato-κ2O,O′)nickel(II)] methanol hemisolvate
title_full Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-olato-κ4N2,O:O,N2′]bis[(acetato-κ2O,O′)nickel(II)] methanol hemisolvate
title_fullStr Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-olato-κ4N2,O:O,N2′]bis[(acetato-κ2O,O′)nickel(II)] methanol hemisolvate
title_full_unstemmed Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-olato-κ4N2,O:O,N2′]bis[(acetato-κ2O,O′)nickel(II)] methanol hemisolvate
title_sort bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-olato-κ4n2,o:o,n2′]bis[(acetato-κ2o,o′)nickel(ii)] methanol hemisolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-01-01
description In the title complex, [Ni2(C13H11F2N6O)2(C2H3O2)2]·0.5CH3OH, there are two half-molecules in the asymmetric unit. The two centrosymmetrically related NiII atoms, each attached to an acetate ligand, are linked by two fluconazole ligands. Each NiII atom is six-coordinated in a distorted octahedral geometry by two N atoms of the triazole groups and two bridging O atoms from two different fluconazole ligands and two O atoms from a chelating acetate ligand. In the crystal structure, the half-occupied methanol solvent molecule is linked to a triazole group via an O—H...N hydrogen bond.
url http://scripts.iucr.org/cgi-bin/paper?S160053680905377X
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