Pseudo-enantiomeric chiral components and formation of the helical micro- and nanostructures in charge-transfer complexes

Pseudo-enantiomeric chiral components and formation of the helical micro- and nanostructures in charge-transfer complexes

Helical organic micro- and nanostructures are formed by a charge-transfer complex, cinchonidine-TCNQ. These unusual forms result from the chirality, the steric structure and specific interactions of cinchonidine molecules. These materials are semiconductors (10−4 S cm−1), with the typical absorption...

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Main Authors: Jerzy J. Langer, Grzegorz Hreczycho
Format: Article
Language:English
Published: The Royal Society 2018-01-01
Series:Royal Society Open Science
Subjects:
conductive ct complexes
helical micro- and nanostructures
tcnq
Online Access:https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.171499
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spelling doaj-04e75d2cc81447f09eaf55da5cc20efa2020-11-25T03:06:28ZengThe Royal SocietyRoyal Society Open Science2054-57032018-01-015310.1098/rsos.171499171499Pseudo-enantiomeric chiral components and formation of the helical micro- and nanostructures in charge-transfer complexesJerzy J. LangerGrzegorz HreczychoHelical organic micro- and nanostructures are formed by a charge-transfer complex, cinchonidine-TCNQ. These unusual forms result from the chirality, the steric structure and specific interactions of cinchonidine molecules. These materials are semiconductors (10−4 S cm−1), with the typical absorption spectra in IR and UV-vis, but also have a characteristic of CD spectrum. Surprisingly, conductive micro and nano helices are not formed in pseudo-enantiomeric cinchonine, i.e. the complex of cinchonine and TCNQ.https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.171499conductive ct complexeshelical micro- and nanostructurestcnq
collection DOAJ
language English
format Article
sources DOAJ
author Jerzy J. Langer
Grzegorz Hreczycho
spellingShingle Jerzy J. Langer
Grzegorz Hreczycho
Pseudo-enantiomeric chiral components and formation of the helical micro- and nanostructures in charge-transfer complexes
Royal Society Open Science
conductive ct complexes
helical micro- and nanostructures
tcnq
author_facet Jerzy J. Langer
Grzegorz Hreczycho
author_sort Jerzy J. Langer
title Pseudo-enantiomeric chiral components and formation of the helical micro- and nanostructures in charge-transfer complexes
title_short Pseudo-enantiomeric chiral components and formation of the helical micro- and nanostructures in charge-transfer complexes
title_full Pseudo-enantiomeric chiral components and formation of the helical micro- and nanostructures in charge-transfer complexes
title_fullStr Pseudo-enantiomeric chiral components and formation of the helical micro- and nanostructures in charge-transfer complexes
title_full_unstemmed Pseudo-enantiomeric chiral components and formation of the helical micro- and nanostructures in charge-transfer complexes
title_sort pseudo-enantiomeric chiral components and formation of the helical micro- and nanostructures in charge-transfer complexes
publisher The Royal Society
series Royal Society Open Science
issn 2054-5703
publishDate 2018-01-01
description Helical organic micro- and nanostructures are formed by a charge-transfer complex, cinchonidine-TCNQ. These unusual forms result from the chirality, the steric structure and specific interactions of cinchonidine molecules. These materials are semiconductors (10−4 S cm−1), with the typical absorption spectra in IR and UV-vis, but also have a characteristic of CD spectrum. Surprisingly, conductive micro and nano helices are not formed in pseudo-enantiomeric cinchonine, i.e. the complex of cinchonine and TCNQ.
topic conductive ct complexes
helical micro- and nanostructures
tcnq
url https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.171499
work_keys_str_mv AT jerzyjlanger pseudoenantiomericchiralcomponentsandformationofthehelicalmicroandnanostructuresinchargetransfercomplexes
AT grzegorzhreczycho pseudoenantiomericchiralcomponentsandformationofthehelicalmicroandnanostructuresinchargetransfercomplexes
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