Hexaaquacopper(II) bis(tetrafluoridoborate)–pyrazine 1,4-dioxide (1/3)
The crystal structure of the title compound, [Cu(H2O)6](BF4)2·3C4H4N2O2, comprises discrete [Cu(H2O)6]2+ cations and BF4− anions along with three equivalents of pyrazine 1,4-dioxide (pzdo). The hexaaquacopper(II) ion and all three pzdo molecules lie about crystallographic inversio...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813007629 |
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doaj-0321dc06d91a4c13a63684b0838c4f1e2020-11-24T21:26:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-04-01694m229m23010.1107/S1600536813007629Hexaaquacopper(II) bis(tetrafluoridoborate)–pyrazine 1,4-dioxide (1/3)Jan L. WikairaChristopher P. LandeeMark M. TurnbullThe crystal structure of the title compound, [Cu(H2O)6](BF4)2·3C4H4N2O2, comprises discrete [Cu(H2O)6]2+ cations and BF4− anions along with three equivalents of pyrazine 1,4-dioxide (pzdo). The hexaaquacopper(II) ion and all three pzdo molecules lie about crystallographic inversion centers. The lattice is supported by an extensive hydrogen-bonding network. O—H...O hydrogen bonding between the [Cu(H2O)6]2+ and pzdo units creates a pseudo-hexagonal lattice parallel to the bc plane. The BF4− anions lie in the voids of that lattice, held in place by O—H...F hydrogen bonds, and also generate BF4−–pzdo–BF4−–pzdo stacks via short F...N contacts [2.866 (3)–3.283 (4) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536813007629 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Jan L. Wikaira Christopher P. Landee Mark M. Turnbull |
| spellingShingle |
Jan L. Wikaira Christopher P. Landee Mark M. Turnbull Hexaaquacopper(II) bis(tetrafluoridoborate)–pyrazine 1,4-dioxide (1/3) Acta Crystallographica Section E |
| author_facet |
Jan L. Wikaira Christopher P. Landee Mark M. Turnbull |
| author_sort |
Jan L. Wikaira |
| title |
Hexaaquacopper(II) bis(tetrafluoridoborate)–pyrazine 1,4-dioxide (1/3) |
| title_short |
Hexaaquacopper(II) bis(tetrafluoridoborate)–pyrazine 1,4-dioxide (1/3) |
| title_full |
Hexaaquacopper(II) bis(tetrafluoridoborate)–pyrazine 1,4-dioxide (1/3) |
| title_fullStr |
Hexaaquacopper(II) bis(tetrafluoridoborate)–pyrazine 1,4-dioxide (1/3) |
| title_full_unstemmed |
Hexaaquacopper(II) bis(tetrafluoridoborate)–pyrazine 1,4-dioxide (1/3) |
| title_sort |
hexaaquacopper(ii) bis(tetrafluoridoborate)–pyrazine 1,4-dioxide (1/3) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2013-04-01 |
| description |
The crystal structure of the title compound, [Cu(H2O)6](BF4)2·3C4H4N2O2, comprises discrete [Cu(H2O)6]2+ cations and BF4− anions along with three equivalents of pyrazine 1,4-dioxide (pzdo). The hexaaquacopper(II) ion and all three pzdo molecules lie about crystallographic inversion centers. The lattice is supported by an extensive hydrogen-bonding network. O—H...O hydrogen bonding between the [Cu(H2O)6]2+ and pzdo units creates a pseudo-hexagonal lattice parallel to the bc plane. The BF4− anions lie in the voids of that lattice, held in place by O—H...F hydrogen bonds, and also generate BF4−–pzdo–BF4−–pzdo stacks via short F...N contacts [2.866 (3)–3.283 (4) Å]. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536813007629 |
| work_keys_str_mv |
AT janlwikaira hexaaquacopperiibistetrafluoridoborate8211pyrazine14dioxide13 AT christopherplandee hexaaquacopperiibistetrafluoridoborate8211pyrazine14dioxide13 AT markmturnbull hexaaquacopperiibistetrafluoridoborate8211pyrazine14dioxide13 |
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