N-(3-Chlorophenyl)-2-methylbenzamide
The conformation of the N—H bond in the structure of the title compound, C14H12ClNO, is anti to the meta-chloro substituent in the aniline ring, while the C=O bond is syn to the ortho-methyl substituent in the benzoyl ring. The conformations of the N—H and C=O bonds are anti to e...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808010143 |
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doaj-03062b3d4197497d9d4ddf31449499cd2020-11-24T22:08:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645o861o86110.1107/S1600536808010143N-(3-Chlorophenyl)-2-methylbenzamideHartmut FuessB. P. SowmyaSabine ForoB. Thimme GowdaThe conformation of the N—H bond in the structure of the title compound, C14H12ClNO, is anti to the meta-chloro substituent in the aniline ring, while the C=O bond is syn to the ortho-methyl substituent in the benzoyl ring. The conformations of the N—H and C=O bonds are anti to each other, similar to those observed in 2-methyl-N-(3-methylphenyl)benzamide (N3MP2MBA). The –NHC(=O)– group makes a dihedral angle of 55.8 (7)° with the benzoyl ring, while the angle between the benzoyl and aniline rings is 37.5 (1)°; the respective values for N3MP2MBA are 55.2 (7) and 36.2 (1)°. N—H...O hydrogen bonds link the molecules into infinite chains running along the c axis.http://scripts.iucr.org/cgi-bin/paper?S1600536808010143 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Hartmut Fuess B. P. Sowmya Sabine Foro B. Thimme Gowda |
| spellingShingle |
Hartmut Fuess B. P. Sowmya Sabine Foro B. Thimme Gowda N-(3-Chlorophenyl)-2-methylbenzamide Acta Crystallographica Section E |
| author_facet |
Hartmut Fuess B. P. Sowmya Sabine Foro B. Thimme Gowda |
| author_sort |
Hartmut Fuess |
| title |
N-(3-Chlorophenyl)-2-methylbenzamide |
| title_short |
N-(3-Chlorophenyl)-2-methylbenzamide |
| title_full |
N-(3-Chlorophenyl)-2-methylbenzamide |
| title_fullStr |
N-(3-Chlorophenyl)-2-methylbenzamide |
| title_full_unstemmed |
N-(3-Chlorophenyl)-2-methylbenzamide |
| title_sort |
n-(3-chlorophenyl)-2-methylbenzamide |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2008-05-01 |
| description |
The conformation of the N—H bond in the structure of the title compound, C14H12ClNO, is anti to the meta-chloro substituent in the aniline ring, while the C=O bond is syn to the ortho-methyl substituent in the benzoyl ring. The conformations of the N—H and C=O bonds are anti to each other, similar to those observed in 2-methyl-N-(3-methylphenyl)benzamide (N3MP2MBA). The –NHC(=O)– group makes a dihedral angle of 55.8 (7)° with the benzoyl ring, while the angle between the benzoyl and aniline rings is 37.5 (1)°; the respective values for N3MP2MBA are 55.2 (7) and 36.2 (1)°. N—H...O hydrogen bonds link the molecules into infinite chains running along the c axis. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536808010143 |
| work_keys_str_mv |
AT hartmutfuess n3chlorophenyl2methylbenzamide AT bpsowmya n3chlorophenyl2methylbenzamide AT sabineforo n3chlorophenyl2methylbenzamide AT bthimmegowda n3chlorophenyl2methylbenzamide |
| _version_ |
1725816312580538368 |