Tetraphenylphosphonium hydrogen oxalate

Tetraphenylphosphonium hydrogen oxalate

In the title compound, C24H20P+·C2HO4−, two symmetry-independent ion pairs are present. The cations aggregate into puckered sheets via zigzag infinite chains of sixfold phenyl embraces and parallel fourfold phenyl embraces, while the anions form hydrogen-bonded chains between the...

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Main Authors: Philip A. W. Dean, Donald C. Craig, Marcia L. Scudder, Ian G. Dance
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680706463X
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spelling doaj-02d3ee404ec843a290a7ce13f2a480032020-11-25T02:12:51ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641o243o24310.1107/S160053680706463XTetraphenylphosphonium hydrogen oxalatePhilip A. W. DeanDonald C. CraigMarcia L. ScudderIan G. DanceIn the title compound, C24H20P+·C2HO4−, two symmetry-independent ion pairs are present. The cations aggregate into puckered sheets via zigzag infinite chains of sixfold phenyl embraces and parallel fourfold phenyl embraces, while the anions form hydrogen-bonded chains between the sheets of cations. In the two independent oxalate anions, the angles between the normals to the two least-squares carboxylate COO planes are unusually large, viz. 72.5 (1) and 82.1 (1)°.http://scripts.iucr.org/cgi-bin/paper?S160053680706463X
collection DOAJ
language English
format Article
sources DOAJ
author Philip A. W. Dean
Donald C. Craig
Marcia L. Scudder
Ian G. Dance
spellingShingle Philip A. W. Dean
Donald C. Craig
Marcia L. Scudder
Ian G. Dance
Tetraphenylphosphonium hydrogen oxalate
Acta Crystallographica Section E
author_facet Philip A. W. Dean
Donald C. Craig
Marcia L. Scudder
Ian G. Dance
author_sort Philip A. W. Dean
title Tetraphenylphosphonium hydrogen oxalate
title_short Tetraphenylphosphonium hydrogen oxalate
title_full Tetraphenylphosphonium hydrogen oxalate
title_fullStr Tetraphenylphosphonium hydrogen oxalate
title_full_unstemmed Tetraphenylphosphonium hydrogen oxalate
title_sort tetraphenylphosphonium hydrogen oxalate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description In the title compound, C24H20P+·C2HO4−, two symmetry-independent ion pairs are present. The cations aggregate into puckered sheets via zigzag infinite chains of sixfold phenyl embraces and parallel fourfold phenyl embraces, while the anions form hydrogen-bonded chains between the sheets of cations. In the two independent oxalate anions, the angles between the normals to the two least-squares carboxylate COO planes are unusually large, viz. 72.5 (1) and 82.1 (1)°.
url http://scripts.iucr.org/cgi-bin/paper?S160053680706463X
work_keys_str_mv AT philipawdean tetraphenylphosphoniumhydrogenoxalate
AT donaldccraig tetraphenylphosphoniumhydrogenoxalate
AT marcialscudder tetraphenylphosphoniumhydrogenoxalate
AT iangdance tetraphenylphosphoniumhydrogenoxalate
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