Correlation between thermo-mechanical properties and network structure in GexS100–x chalcogenide glasses
GexS100-x glasses with a wide compositional range of 10 ≤ x ≤ 43 (mol%) were prepared for the investigation and understanding of compositional trends of physical properties and structural features in this binary chalcogenide glasses. Both of mechanical and thermal properties were studied by the tech...
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doaj-02130c2bfbdc4a89ac555f75efc36a542020-11-24T21:18:26ZengElsevierJournal of Non-Crystalline Solids: X2590-15912019-03-011Correlation between thermo-mechanical properties and network structure in GexS100–x chalcogenide glassesErwei Zhu0Yongxing Liu1Xing Sun2Guoliang Yin3Qing Jiao4Shixun Dai5Changgui Lin6Laboratory of Infrared Materials and Devices, The Research Institute of Advanced Technologies, Ningbo University, Ningbo 315211, China; Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province, Ningbo 315211, ChinaLaboratory of Infrared Materials and Devices, The Research Institute of Advanced Technologies, Ningbo University, Ningbo 315211, China; Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province, Ningbo 315211, ChinaYunnan KIRO-CH Photonics Co., Ltd, No. 5 Hongwai Road, Economic and Technological Development Zone, Kunming, ChinaYunnan KIRO-CH Photonics Co., Ltd, No. 5 Hongwai Road, Economic and Technological Development Zone, Kunming, ChinaLaboratory of Infrared Materials and Devices, The Research Institute of Advanced Technologies, Ningbo University, Ningbo 315211, China; Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province, Ningbo 315211, ChinaLaboratory of Infrared Materials and Devices, The Research Institute of Advanced Technologies, Ningbo University, Ningbo 315211, China; Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province, Ningbo 315211, ChinaLaboratory of Infrared Materials and Devices, The Research Institute of Advanced Technologies, Ningbo University, Ningbo 315211, China; Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province, Ningbo 315211, China; Corresponding author at: Laboratory of Infrared Materials and Devices, The Research Institute of Advanced Technologies, Ningbo University, Ningbo 315211, ChinaGexS100-x glasses with a wide compositional range of 10 ≤ x ≤ 43 (mol%) were prepared for the investigation and understanding of compositional trends of physical properties and structural features in this binary chalcogenide glasses. Both of mechanical and thermal properties were studied by the techniques of micro-indentation, resonant ultrasound spectroscopy, dilatometer, and DSC. The compositional evolution of network structure was discussed with the detailed investigation of Raman spectra. The thermo-mechanical properties, including hardness, thermal expansion coefficient, and elastic modulus, are firstly studied systematically in this binary glass system. Together with structural model theories, the correlation between thermo-mechanical properties and network structure of GexS100-x glasses is established. This work further clarify the composition-structure-property relationship of chalcogenide glasses, which would contribute to the compositional design of novel glasses with elaborate properties. Keywords: Chalcogenide glass, Network structure, Mechanical property, Thermal propertyhttp://www.sciencedirect.com/science/article/pii/S2590159119300287 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Erwei Zhu Yongxing Liu Xing Sun Guoliang Yin Qing Jiao Shixun Dai Changgui Lin |
spellingShingle |
Erwei Zhu Yongxing Liu Xing Sun Guoliang Yin Qing Jiao Shixun Dai Changgui Lin Correlation between thermo-mechanical properties and network structure in GexS100–x chalcogenide glasses Journal of Non-Crystalline Solids: X |
author_facet |
Erwei Zhu Yongxing Liu Xing Sun Guoliang Yin Qing Jiao Shixun Dai Changgui Lin |
author_sort |
Erwei Zhu |
title |
Correlation between thermo-mechanical properties and network structure in GexS100–x chalcogenide glasses |
title_short |
Correlation between thermo-mechanical properties and network structure in GexS100–x chalcogenide glasses |
title_full |
Correlation between thermo-mechanical properties and network structure in GexS100–x chalcogenide glasses |
title_fullStr |
Correlation between thermo-mechanical properties and network structure in GexS100–x chalcogenide glasses |
title_full_unstemmed |
Correlation between thermo-mechanical properties and network structure in GexS100–x chalcogenide glasses |
title_sort |
correlation between thermo-mechanical properties and network structure in gexs100–x chalcogenide glasses |
publisher |
Elsevier |
series |
Journal of Non-Crystalline Solids: X |
issn |
2590-1591 |
publishDate |
2019-03-01 |
description |
GexS100-x glasses with a wide compositional range of 10 ≤ x ≤ 43 (mol%) were prepared for the investigation and understanding of compositional trends of physical properties and structural features in this binary chalcogenide glasses. Both of mechanical and thermal properties were studied by the techniques of micro-indentation, resonant ultrasound spectroscopy, dilatometer, and DSC. The compositional evolution of network structure was discussed with the detailed investigation of Raman spectra. The thermo-mechanical properties, including hardness, thermal expansion coefficient, and elastic modulus, are firstly studied systematically in this binary glass system. Together with structural model theories, the correlation between thermo-mechanical properties and network structure of GexS100-x glasses is established. This work further clarify the composition-structure-property relationship of chalcogenide glasses, which would contribute to the compositional design of novel glasses with elaborate properties. Keywords: Chalcogenide glass, Network structure, Mechanical property, Thermal property |
url |
http://www.sciencedirect.com/science/article/pii/S2590159119300287 |
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