Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System

Abstract Palladium-catalysed competitive intramolecular C–N and C–C coupling of 2-amino-2′-bromodiarylsulfones has been carried out based on 1,8-peri-interactions for the synthesis of phenothiazinedioxide and benzonaphthathiophenedioxide derivatives. A DFT study has been performed that provides supp...

Full description

Bibliographic Details
Main Authors: Sudarshan Debnath, Shovan Mondal
Format: Article
Language:English
Published: Georg Thieme Verlag KG 2019-01-01
Series:SynOpen
Subjects:
Online Access:http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611667
id doaj-01a5a349262249b584897eb221f61574
record_format Article
spelling doaj-01a5a349262249b584897eb221f615742020-11-25T03:23:30ZengGeorg Thieme Verlag KGSynOpen2509-93962019-01-010301111510.1055/s-0037-1611667Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene SystemSudarshan DebnathShovan Mondal0Department of Chemistry, Syamsundar CollegeAbstract Palladium-catalysed competitive intramolecular C–N and C–C coupling of 2-amino-2′-bromodiarylsulfones has been carried out based on 1,8-peri-interactions for the synthesis of phenothiazinedioxide and benzonaphthathiophenedioxide derivatives. A DFT study has been performed that provides support for the influence of the 1,8-peri-interaction.http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611667naphthalene1,8-peri-interactioncyclizationfused-ringheterocycles
collection DOAJ
language English
format Article
sources DOAJ
author Sudarshan Debnath
Shovan Mondal
spellingShingle Sudarshan Debnath
Shovan Mondal
Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System
SynOpen
naphthalene
1,8-peri-interaction
cyclization
fused-ring
heterocycles
author_facet Sudarshan Debnath
Shovan Mondal
author_sort Sudarshan Debnath
title Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System
title_short Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System
title_full Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System
title_fullStr Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System
title_full_unstemmed Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System
title_sort palladium-catalysed intramolecular c–n versus c–c coupling: the effect of 1,8-peri-interaction in the naphthalene system
publisher Georg Thieme Verlag KG
series SynOpen
issn 2509-9396
publishDate 2019-01-01
description Abstract Palladium-catalysed competitive intramolecular C–N and C–C coupling of 2-amino-2′-bromodiarylsulfones has been carried out based on 1,8-peri-interactions for the synthesis of phenothiazinedioxide and benzonaphthathiophenedioxide derivatives. A DFT study has been performed that provides support for the influence of the 1,8-peri-interaction.
topic naphthalene
1,8-peri-interaction
cyclization
fused-ring
heterocycles
url http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611667
work_keys_str_mv AT sudarshandebnath palladiumcatalysedintramolecularcnversuscccouplingtheeffectof18periinteractioninthenaphthalenesystem
AT shovanmondal palladiumcatalysedintramolecularcnversuscccouplingtheeffectof18periinteractioninthenaphthalenesystem
_version_ 1724605900684001280