Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System
Abstract Palladium-catalysed competitive intramolecular C–N and C–C coupling of 2-amino-2′-bromodiarylsulfones has been carried out based on 1,8-peri-interactions for the synthesis of phenothiazinedioxide and benzonaphthathiophenedioxide derivatives. A DFT study has been performed that provides supp...
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Georg Thieme Verlag KG
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Online Access: | http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611667 |
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doaj-01a5a349262249b584897eb221f615742020-11-25T03:23:30ZengGeorg Thieme Verlag KGSynOpen2509-93962019-01-010301111510.1055/s-0037-1611667Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene SystemSudarshan DebnathShovan Mondal0Department of Chemistry, Syamsundar CollegeAbstract Palladium-catalysed competitive intramolecular C–N and C–C coupling of 2-amino-2′-bromodiarylsulfones has been carried out based on 1,8-peri-interactions for the synthesis of phenothiazinedioxide and benzonaphthathiophenedioxide derivatives. A DFT study has been performed that provides support for the influence of the 1,8-peri-interaction.http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611667naphthalene1,8-peri-interactioncyclizationfused-ringheterocycles |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Sudarshan Debnath Shovan Mondal |
spellingShingle |
Sudarshan Debnath Shovan Mondal Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System SynOpen naphthalene 1,8-peri-interaction cyclization fused-ring heterocycles |
author_facet |
Sudarshan Debnath Shovan Mondal |
author_sort |
Sudarshan Debnath |
title |
Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System |
title_short |
Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System |
title_full |
Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System |
title_fullStr |
Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System |
title_full_unstemmed |
Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System |
title_sort |
palladium-catalysed intramolecular c–n versus c–c coupling: the effect of 1,8-peri-interaction in the naphthalene system |
publisher |
Georg Thieme Verlag KG |
series |
SynOpen |
issn |
2509-9396 |
publishDate |
2019-01-01 |
description |
Abstract
Palladium-catalysed competitive intramolecular C–N and C–C coupling of 2-amino-2′-bromodiarylsulfones has been carried out based on 1,8-peri-interactions for the synthesis of phenothiazinedioxide and benzonaphthathiophenedioxide derivatives. A DFT study has been performed that provides support for the influence of the 1,8-peri-interaction. |
topic |
naphthalene 1,8-peri-interaction cyclization fused-ring heterocycles |
url |
http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611667 |
work_keys_str_mv |
AT sudarshandebnath palladiumcatalysedintramolecularcnversuscccouplingtheeffectof18periinteractioninthenaphthalenesystem AT shovanmondal palladiumcatalysedintramolecularcnversuscccouplingtheeffectof18periinteractioninthenaphthalenesystem |
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1724605900684001280 |