Rheological Properties Related to Extrusion of Polyolefins

Rheological properties related to the extrusion of polyolefins are the shear viscosity, the elongational viscosity, the slip velocity and their temperature- and pressure-dependencies. These properties are measured in the rheology lab mainly via a parallel-plate rheometer and a capillary rheometer. T...

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Bibliographic Details
Main Authors: Evan Mitsoulis, Savvas G. Hatzikiriakos
Format: Article
Language:English
Published: MDPI AG 2021-02-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/13/4/489
Description
Summary:Rheological properties related to the extrusion of polyolefins are the shear viscosity, the elongational viscosity, the slip velocity and their temperature- and pressure-dependencies. These properties are measured in the rheology lab mainly via a parallel-plate rheometer and a capillary rheometer. Then appropriate rheological models have to be used to account for all these properties. Such models are either viscous (e.g, the Cross model) or viscoelastic (e.g, the K-BKZ model). The latter gives the best fitting of the experimental data and offers excellent results in numerical simulations, especially in extrusion flows. Wall slip effects are also found and measured by rheometric flows. Modeling of extrusion flows should make use of appropriate slip models that take into effect the various slip parameters, including the effects of shear stress, molecular characteristics, temperature and pressure on the slip velocity. In this paper the importance of these properties in extrusion are discussed.
ISSN:2073-4360