Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II)

In the title complex, [Cu(C16H24N3S2)2], the CuII atom is coordinated by two azomethine N and two thiolate S atoms of the chelating Schiff base ligands, resulting in a distorted square-planar coordination environment. The S—Cu—N chelating angle is of 84.41 (5)°. The CuII atom is located on a crystal...

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Main Authors: E. Zangrando, M. S. Begum, R. Miyatake, M. C. Sheikh, Md. M. Hossain
Format: Article
Language:English
Published: International Union of Crystallography 2015-06-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015009342
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spelling doaj-01402b7845f044be912eca86470d2c612020-11-24T21:23:48ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-06-0171670670810.1107/S2056989015009342ff2136Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II)E. Zangrando0M. S. Begum1R. Miyatake2M. C. Sheikh3Md. M. Hossain4Department of Chemical and Pharmaceutical Sciences, via Giorgieri 1, 34127 Trieste, ItalyDepartment of Chemistry, Rajshahi University, Rajshahi-6205, BangladeshCenter for Environmental Conservation and Research Safety, University of Toyama, 3190 Gofuku, Toyama, 930-8555, JapanDepartment of Applied Chemistry, Faculty of Engineering, University of Toyama, 3190 Gofuku, Toyama 930-8555, JapanDepartment of Chemistry, Rajshahi University, Rajshahi-6205, BangladeshIn the title complex, [Cu(C16H24N3S2)2], the CuII atom is coordinated by two azomethine N and two thiolate S atoms of the chelating Schiff base ligands, resulting in a distorted square-planar coordination environment. The S—Cu—N chelating angle is of 84.41 (5)°. The CuII atom is located on a crystallographic inversion centre, leading to a trans configuration of the N,S-chelating ligands.http://scripts.iucr.org/cgi-bin/paper?S2056989015009342crystal structurecopper(II) complexdithiocarbazate ligand
collection DOAJ
language English
format Article
sources DOAJ
author E. Zangrando
M. S. Begum
R. Miyatake
M. C. Sheikh
Md. M. Hossain
spellingShingle E. Zangrando
M. S. Begum
R. Miyatake
M. C. Sheikh
Md. M. Hossain
Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II)
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
copper(II) complex
dithiocarbazate ligand
author_facet E. Zangrando
M. S. Begum
R. Miyatake
M. C. Sheikh
Md. M. Hossain
author_sort E. Zangrando
title Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II)
title_short Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II)
title_full Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II)
title_fullStr Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II)
title_full_unstemmed Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II)
title_sort crystal structure of bis{s-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2n3,s}copper(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2015-06-01
description In the title complex, [Cu(C16H24N3S2)2], the CuII atom is coordinated by two azomethine N and two thiolate S atoms of the chelating Schiff base ligands, resulting in a distorted square-planar coordination environment. The S—Cu—N chelating angle is of 84.41 (5)°. The CuII atom is located on a crystallographic inversion centre, leading to a trans configuration of the N,S-chelating ligands.
topic crystal structure
copper(II) complex
dithiocarbazate ligand
url http://scripts.iucr.org/cgi-bin/paper?S2056989015009342
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AT rmiyatake crystalstructureofbisshexyl34dimethylaminobenzylidenedithiocarbazatok2n3scopperii
AT mcsheikh crystalstructureofbisshexyl34dimethylaminobenzylidenedithiocarbazatok2n3scopperii
AT mdmhossain crystalstructureofbisshexyl34dimethylaminobenzylidenedithiocarbazatok2n3scopperii
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