Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II)
In the title complex, [Cu(C16H24N3S2)2], the CuII atom is coordinated by two azomethine N and two thiolate S atoms of the chelating Schiff base ligands, resulting in a distorted square-planar coordination environment. The S—Cu—N chelating angle is of 84.41 (5)°. The CuII atom is located on a crystal...
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International Union of Crystallography
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doaj-01402b7845f044be912eca86470d2c612020-11-24T21:23:48ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-06-0171670670810.1107/S2056989015009342ff2136Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II)E. Zangrando0M. S. Begum1R. Miyatake2M. C. Sheikh3Md. M. Hossain4Department of Chemical and Pharmaceutical Sciences, via Giorgieri 1, 34127 Trieste, ItalyDepartment of Chemistry, Rajshahi University, Rajshahi-6205, BangladeshCenter for Environmental Conservation and Research Safety, University of Toyama, 3190 Gofuku, Toyama, 930-8555, JapanDepartment of Applied Chemistry, Faculty of Engineering, University of Toyama, 3190 Gofuku, Toyama 930-8555, JapanDepartment of Chemistry, Rajshahi University, Rajshahi-6205, BangladeshIn the title complex, [Cu(C16H24N3S2)2], the CuII atom is coordinated by two azomethine N and two thiolate S atoms of the chelating Schiff base ligands, resulting in a distorted square-planar coordination environment. The S—Cu—N chelating angle is of 84.41 (5)°. The CuII atom is located on a crystallographic inversion centre, leading to a trans configuration of the N,S-chelating ligands.http://scripts.iucr.org/cgi-bin/paper?S2056989015009342crystal structurecopper(II) complexdithiocarbazate ligand |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
E. Zangrando M. S. Begum R. Miyatake M. C. Sheikh Md. M. Hossain |
spellingShingle |
E. Zangrando M. S. Begum R. Miyatake M. C. Sheikh Md. M. Hossain Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II) Acta Crystallographica Section E: Crystallographic Communications crystal structure copper(II) complex dithiocarbazate ligand |
author_facet |
E. Zangrando M. S. Begum R. Miyatake M. C. Sheikh Md. M. Hossain |
author_sort |
E. Zangrando |
title |
Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II) |
title_short |
Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II) |
title_full |
Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II) |
title_fullStr |
Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II) |
title_full_unstemmed |
Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II) |
title_sort |
crystal structure of bis{s-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2n3,s}copper(ii) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E: Crystallographic Communications |
issn |
2056-9890 |
publishDate |
2015-06-01 |
description |
In the title complex, [Cu(C16H24N3S2)2], the CuII atom is coordinated by two azomethine N and two thiolate S atoms of the chelating Schiff base ligands, resulting in a distorted square-planar coordination environment. The S—Cu—N chelating angle is of 84.41 (5)°. The CuII atom is located on a crystallographic inversion centre, leading to a trans configuration of the N,S-chelating ligands. |
topic |
crystal structure copper(II) complex dithiocarbazate ligand |
url |
http://scripts.iucr.org/cgi-bin/paper?S2056989015009342 |
work_keys_str_mv |
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