Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II)

Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II)

In the title complex, [Cu(C16H24N3S2)2], the CuII atom is coordinated by two azomethine N and two thiolate S atoms of the chelating Schiff base ligands, resulting in a distorted square-planar coordination environment. The S—Cu—N chelating angle is of 84.41 (5)°. The CuII atom is located on a crystal...

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Bibliographic Details
Main Authors: E. Zangrando, M. S. Begum, R. Miyatake, M. C. Sheikh, Md. M. Hossain
Format: Article
Language:English
Published: International Union of Crystallography 2015-06-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
copper(II) complex
dithiocarbazate ligand
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015009342
Description
Summary:In the title complex, [Cu(C16H24N3S2)2], the CuII atom is coordinated by two azomethine N and two thiolate S atoms of the chelating Schiff base ligands, resulting in a distorted square-planar coordination environment. The S—Cu—N chelating angle is of 84.41 (5)°. The CuII atom is located on a crystallographic inversion centre, leading to a trans configuration of the N,S-chelating ligands.
ISSN:2056-9890

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