Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I)

The dimeric title complex, [Cu2(C14H9N2O2)2], resides on a center of symmetry. In the crystal, the molecules are packed via π–π stacking interactions alternating between imidazole and benzene rings [mean interplanar distances = 3.754 (3) and 3.62...

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Main Authors: Zheng-Yu Su, Ke-Wei Lei, Jie Li, Dong-Guo Xia
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810046040
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spelling doaj-00721eb298024274a4d8a512b8fa9a082020-11-25T00:27:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1582m158210.1107/S1600536810046040Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I)Zheng-Yu SuKe-Wei LeiJie LiDong-Guo XiaThe dimeric title complex, [Cu2(C14H9N2O2)2], resides on a center of symmetry. In the crystal, the molecules are packed via π–π stacking interactions alternating between imidazole and benzene rings [mean interplanar distances = 3.754 (3) and 3.624 (3) Å]. An intermolecular N—H...O hydrogen bond links the dimers together. The two-coordinate CuI atom displays an O—Cu—N bond angle of 176.3 (2)°. The Cu...Cu distance within the dimer is 5.100 (2) Å. http://scripts.iucr.org/cgi-bin/paper?S1600536810046040
collection DOAJ
language English
format Article
sources DOAJ
author Zheng-Yu Su
Ke-Wei Lei
Jie Li
Dong-Guo Xia
spellingShingle Zheng-Yu Su
Ke-Wei Lei
Jie Li
Dong-Guo Xia
Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I)
Acta Crystallographica Section E
author_facet Zheng-Yu Su
Ke-Wei Lei
Jie Li
Dong-Guo Xia
author_sort Zheng-Yu Su
title Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I)
title_short Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I)
title_full Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I)
title_fullStr Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I)
title_full_unstemmed Bis[μ-3-(1H-benzimidazol-2-yl)benzoato]dicopper(I)
title_sort bis[μ-3-(1h-benzimidazol-2-yl)benzoato]dicopper(i)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description The dimeric title complex, [Cu2(C14H9N2O2)2], resides on a center of symmetry. In the crystal, the molecules are packed via π–π stacking interactions alternating between imidazole and benzene rings [mean interplanar distances = 3.754 (3) and 3.624 (3) Å]. An intermolecular N—H...O hydrogen bond links the dimers together. The two-coordinate CuI atom displays an O—Cu—N bond angle of 176.3 (2)°. The Cu...Cu distance within the dimer is 5.100 (2) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810046040
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AT jieli bisamp95631hbenzimidazol2ylbenzoatodicopperi
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