Synthesis of new pyrrole–pyridine-based ligands using an in situ Suzuki coupling method

Synthesis of new pyrrole–pyridine-based ligands using an in situ Suzuki coupling method

The compounds 6-(pyrrol-2-yl)-2,2‘-bipyridine, 2-(pyrrol-2-yl)-1,10-phenanthroline and 2-(2-(N-methylbenz[d,e]imidazole)-6-(pyrrol-2-yl)-pyridine were synthesized by using an in situ generated boronic acid for the Suzuki coupling. Crystals of the products could be grown and exhibited interesting str...

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Main Authors: Matthias Böttger, Björn Wiegmann, Steffen Schaumburg, Peter G. Jones, Wolfgang Kowalsky, Hans-Hermann Johannes
Format: Article
Language:English
Published: Beilstein-Institut 2012-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
boronic acids
complex chemistry
in situ generation
pyrrole-pyridine
Suzuki coupling
Online Access:https://doi.org/10.3762/bjoc.8.116
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spelling doaj-00671216457b4bb7b42443c6accba62f2021-02-02T04:39:00ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972012-07-01811037104710.3762/bjoc.8.1161860-5397-8-116Synthesis of new pyrrole–pyridine-based ligands using an in situ Suzuki coupling methodMatthias Böttger0Björn Wiegmann1Steffen Schaumburg2Peter G. Jones3Wolfgang Kowalsky4Hans-Hermann Johannes5Labor für Elektrooptik am Institut für Hochfrequenztechnik, Technische Universität Braunschweig, Bienroder Weg 94, 38106 Braunschweig, GermanyLabor für Elektrooptik am Institut für Hochfrequenztechnik, Technische Universität Braunschweig, Bienroder Weg 94, 38106 Braunschweig, GermanyLabor für Elektrooptik am Institut für Hochfrequenztechnik, Technische Universität Braunschweig, Bienroder Weg 94, 38106 Braunschweig, GermanyInstitut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig, GermanyLabor für Elektrooptik am Institut für Hochfrequenztechnik, Technische Universität Braunschweig, Bienroder Weg 94, 38106 Braunschweig, GermanyLabor für Elektrooptik am Institut für Hochfrequenztechnik, Technische Universität Braunschweig, Bienroder Weg 94, 38106 Braunschweig, GermanyThe compounds 6-(pyrrol-2-yl)-2,2‘-bipyridine, 2-(pyrrol-2-yl)-1,10-phenanthroline and 2-(2-(N-methylbenz[d,e]imidazole)-6-(pyrrol-2-yl)-pyridine were synthesized by using an in situ generated boronic acid for the Suzuki coupling. Crystals of the products could be grown and exhibited interesting structures by X-ray analysis, one of them showing a chain-like network with the adjacent molecules linked to each other via intermolecular N–H…N hydrogen bonds.https://doi.org/10.3762/bjoc.8.116boronic acidscomplex chemistryin situ generationpyrrole-pyridineSuzuki coupling
collection DOAJ
language English
format Article
sources DOAJ
author Matthias Böttger
Björn Wiegmann
Steffen Schaumburg
Peter G. Jones
Wolfgang Kowalsky
Hans-Hermann Johannes
spellingShingle Matthias Böttger
Björn Wiegmann
Steffen Schaumburg
Peter G. Jones
Wolfgang Kowalsky
Hans-Hermann Johannes
Synthesis of new pyrrole–pyridine-based ligands using an in situ Suzuki coupling method
Beilstein Journal of Organic Chemistry
boronic acids
complex chemistry
in situ generation
pyrrole-pyridine
Suzuki coupling
author_facet Matthias Böttger
Björn Wiegmann
Steffen Schaumburg
Peter G. Jones
Wolfgang Kowalsky
Hans-Hermann Johannes
author_sort Matthias Böttger
title Synthesis of new pyrrole–pyridine-based ligands using an in situ Suzuki coupling method
title_short Synthesis of new pyrrole–pyridine-based ligands using an in situ Suzuki coupling method
title_full Synthesis of new pyrrole–pyridine-based ligands using an in situ Suzuki coupling method
title_fullStr Synthesis of new pyrrole–pyridine-based ligands using an in situ Suzuki coupling method
title_full_unstemmed Synthesis of new pyrrole–pyridine-based ligands using an in situ Suzuki coupling method
title_sort synthesis of new pyrrole–pyridine-based ligands using an in situ suzuki coupling method
publisher Beilstein-Institut
series Beilstein Journal of Organic Chemistry
issn 1860-5397
publishDate 2012-07-01
description The compounds 6-(pyrrol-2-yl)-2,2‘-bipyridine, 2-(pyrrol-2-yl)-1,10-phenanthroline and 2-(2-(N-methylbenz[d,e]imidazole)-6-(pyrrol-2-yl)-pyridine were synthesized by using an in situ generated boronic acid for the Suzuki coupling. Crystals of the products could be grown and exhibited interesting structures by X-ray analysis, one of them showing a chain-like network with the adjacent molecules linked to each other via intermolecular N–H…N hydrogen bonds.
topic boronic acids
complex chemistry
in situ generation
pyrrole-pyridine
Suzuki coupling
url https://doi.org/10.3762/bjoc.8.116
work_keys_str_mv AT matthiasbottger synthesisofnewpyrrolepyridinebasedligandsusinganinsitusuzukicouplingmethod
AT bjornwiegmann synthesisofnewpyrrolepyridinebasedligandsusinganinsitusuzukicouplingmethod
AT steffenschaumburg synthesisofnewpyrrolepyridinebasedligandsusinganinsitusuzukicouplingmethod
AT petergjones synthesisofnewpyrrolepyridinebasedligandsusinganinsitusuzukicouplingmethod
AT wolfgangkowalsky synthesisofnewpyrrolepyridinebasedligandsusinganinsitusuzukicouplingmethod
AT hanshermannjohannes synthesisofnewpyrrolepyridinebasedligandsusinganinsitusuzukicouplingmethod
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