Highly Regio- and Stereoselective Hydrogermylation of Fluorinated Alkyl Propiolate

Abstract The selective introduction of fluoroalkylated vinylmetals in controlled strategies is a challenging process for many chemists. This study reports the highly regio- and stereoselective synthesis of functionalized vinylgermanes bearing a perfluoroalkyl group from perfluoroalkylated acetyleni...

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Main Authors:	Ranin. Kawtharani, Mirvat Elmasri, Khalil Cherry, Johan Jacquemin, Mohamed Abarbri
Format:	Article
Language:	English
Published:	Georg Thieme Verlag KG 2019-01-01
Series:	SynOpen
Subjects:	regio- and stereoselective hydrogermylation fluorinated ethyl propiolate alcl3 triphenyl- and tributylgermanes fluorinated vinylgermanes
Online Access:	http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611666

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spelling	doaj-0045dc20aa824d6db249d513d0a32b442020-11-25T02:52:39ZengGeorg Thieme Verlag KGSynOpen2509-93962019-01-01030141010.1055/s-0037-1611666Highly Regio- and Stereoselective Hydrogermylation of Fluorinated Alkyl PropiolateRanin. Kawtharani0Mirvat Elmasri1Khalil Cherry2Johan Jacquemin3Mohamed Abarbri4Laboratoire de Physico-Chimie des Matériaux et des Electrolytes pour l’Energie (PCM2E). EA 6299Laboratoire de Chimie Médicinale et de Produit naturels, Université Libanaise, Faculté des Sciences ILaboratoire Matériaux, Catalyse, Environnement et Méthodes Analytiques (MCEMA), Campus Universitaire de Hadat, Université LibanaiseLaboratoire de Physico-Chimie des Matériaux et des Electrolytes pour l’Energie (PCM2E). EA 6299Laboratoire de Physico-Chimie des Matériaux et des Electrolytes pour l’Energie (PCM2E). EA 6299Abstract The selective introduction of fluoroalkylated vinylmetals in controlled strategies is a challenging process for many chemists. This study reports the highly regio- and stereoselective synthesis of functionalized vinylgermanes bearing a perfluoroalkyl group from perfluoroalkylated acetylenic esters via AlCl3-catalyzed hydrogermylation. Regio- and stereoselectivity are highly dependent on the nature of the catalyst and the nature of the fluoroalkyl group of alkyne.http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611666regio- and stereoselective hydrogermylationfluorinated ethyl propiolatealcl3 triphenyl- and tributylgermanesfluorinated vinylgermanes
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Ranin. Kawtharani Mirvat Elmasri Khalil Cherry Johan Jacquemin Mohamed Abarbri
spellingShingle	Ranin. Kawtharani Mirvat Elmasri Khalil Cherry Johan Jacquemin Mohamed Abarbri Highly Regio- and Stereoselective Hydrogermylation of Fluorinated Alkyl Propiolate SynOpen regio- and stereoselective hydrogermylation fluorinated ethyl propiolate alcl3 triphenyl- and tributylgermanes fluorinated vinylgermanes
author_facet	Ranin. Kawtharani Mirvat Elmasri Khalil Cherry Johan Jacquemin Mohamed Abarbri
author_sort	Ranin. Kawtharani
title	Highly Regio- and Stereoselective Hydrogermylation of Fluorinated Alkyl Propiolate
title_short	Highly Regio- and Stereoselective Hydrogermylation of Fluorinated Alkyl Propiolate
title_full	Highly Regio- and Stereoselective Hydrogermylation of Fluorinated Alkyl Propiolate
title_fullStr	Highly Regio- and Stereoselective Hydrogermylation of Fluorinated Alkyl Propiolate
title_full_unstemmed	Highly Regio- and Stereoselective Hydrogermylation of Fluorinated Alkyl Propiolate
title_sort	highly regio- and stereoselective hydrogermylation of fluorinated alkyl propiolate
publisher	Georg Thieme Verlag KG
series	SynOpen
issn	2509-9396
publishDate	2019-01-01
description	Abstract The selective introduction of fluoroalkylated vinylmetals in controlled strategies is a challenging process for many chemists. This study reports the highly regio- and stereoselective synthesis of functionalized vinylgermanes bearing a perfluoroalkyl group from perfluoroalkylated acetylenic esters via AlCl3-catalyzed hydrogermylation. Regio- and stereoselectivity are highly dependent on the nature of the catalyst and the nature of the fluoroalkyl group of alkyne.
topic	regio- and stereoselective hydrogermylation fluorinated ethyl propiolate alcl3 triphenyl- and tributylgermanes fluorinated vinylgermanes
url	http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611666
work_keys_str_mv	AT raninkawtharani highlyregioandstereoselectivehydrogermylationoffluorinatedalkylpropiolate AT mirvatelmasri highlyregioandstereoselectivehydrogermylationoffluorinatedalkylpropiolate AT khalilcherry highlyregioandstereoselectivehydrogermylationoffluorinatedalkylpropiolate AT johanjacquemin highlyregioandstereoselectivehydrogermylationoffluorinatedalkylpropiolate AT mohamedabarbri highlyregioandstereoselectivehydrogermylationoffluorinatedalkylpropiolate
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Highly Regio- and Stereoselective Hydrogermylation of Fluorinated Alkyl Propiolate

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